About the Research
Research Theme
Development of amphydynamic crystalline materials based on organometallic chemistry
Keyword
Amphydynamic crystals, molecular rotors, crystal engineering, organometalic chemistry
Research Outline
My current research project at the ICReDD is focused on the implementation of non-covalent interactions in the design of amphidynamic crystals. Using the principles of the molecular design of organometalic luminophores and crystal engineering I aim to the development of new materials which would combine both stimuli-responsive luminescence properties and molecular motion in a crystalline media.
Research History
Please see my CV.
Representative Research Achievements
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The Halogen Bond with Isocyano Carbon Reduces Isocyanide Odor. A. S. Mikherdov, A. S. Novikov, V. P. Boyarskiy, V. Yu. Kukushkin. Nat. Commun., 2020, 11, 2921.
DOI: 10.1038/s41467-020-16748-x -
(Isocyano Group π-Hole)···[dz2-MII] Interactions at (Isocyanide)[MII] Complexes, where Positively Charged Metal Centers (d8M = Pt, Pd) Act as Nucleophiles. S. A. Katkova, A. S. Mikherdov, M. A. Kinzhalov, A. S. Novikov, A. A. Zolotarev, V. P. Boyarskiy, V. Yu. Kukushkin. Chem. Eur. J., 2019, 25, 8590–8598.
DOI: 10.1002/chem.201901187 -
Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent···Complex Halogen Bonding. M. A. Kinzhalov, M. V. Kashina, A. S. Mikherdov, E. A. Mozheeva, A. S. Novikov, A. S. Smirnov, D. M. Ivanov, M. A. Kryukova, A. Yu. Ivanov, S. N. Smirnov, V. Yu. Kukushkin, K. V. Luzyanin. Angew. Chem. Int. Ed., 2018, 57, 12785–12789.
DOI: 10.1002/anie.201807642 -
Halides Held by Bifurcated Chalcogen–Hydrogen Bonds. Effect of µ(S,N–H)Cl Contacts on Dimerization of Cl(carbene)PdII Species. A. S. Mikherdov, A. S. Novikov, M. A. Kinzhalov, V. P. Boyarskiy, G. L. Starova, A. Yu. Ivanov, V. Yu. Kukushkin. Inorg. Chem., 2018, 57, 3420–3433.
DOI: 10.1021/acs.inorgchem.8b00190 -
Difference in Energy between Two Distinct Types of Chalcogen Bonds Drives Regioisomerization of Binuclear (Diaminocarbene)PdII Complexes. A. S. Mikherdov, M. A. Kinzhalov, A. S. Novikov, V. P. Boyarskiy, I. A. Boyarskaya, D. V. Dar’in, G. L. Starova, V. Yu. Kukushkin. J. Am. Chem. Soc., 2016, 138, 14129-14137.
DOI: 10.1021/jacs.6b09133
Related Research
Publications
2024
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Crystallization-Induced Chirality Transfer in Conformationally Flexible Azahelicene Au(I) Complexes with Circularly Polarized Luminescence Activation
, A. S. Mikherdov, H. Ito, M. Jin, J. Am. Chem. Soc., 2024, ,
DOI: 10.1021/jacs.4c00345
2023
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A Steric-Repulsion-Driven Clutch Stack of Triaryltriazines: Correlated Molecular Rotations and a Thermoresponsive Gearshift in the Crystalline Solid
, R. Kitsu, N. Hammyo, A. Sato-Tomita, M. Mizuno, A. S. Mikherdov, M. Tsitsvero, A. Lyalin, T. Taketsugu, H. Ito, J. Am. Chem. Soc., 2023, 145, 50, 27512-27520
DOI: 10.1021/jacs.3c08909