研究紹介
研究テーマ
Development of amphydynamic crystalline materials based on organometallic chemistry
キーワード
Amphydynamic crystals, molecular rotors, crystal engineering, organometalic chemistry
研究概要
My current research project at the ICReDD is focused on the implementation of non-covalent interactions in the design of amphidynamic crystals. Using the principles of the molecular design of organometalic luminophores and crystal engineering I aim to the development of new materials which would combine both stimuli-responsive luminescence properties and molecular motion in a crystalline media.
経歴
履歴書をご参照ください。
代表的な研究成果
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The Halogen Bond with Isocyano Carbon Reduces Isocyanide Odor. A. S. Mikherdov, A. S. Novikov, V. P. Boyarskiy, V. Yu. Kukushkin. Nat. Commun., 2020, 11, 2921.
DOI: 10.1038/s41467-020-16748-x -
(Isocyano Group π-Hole)···[dz2-MII] Interactions at (Isocyanide)[MII] Complexes, where Positively Charged Metal Centers (d8M = Pt, Pd) Act as Nucleophiles. S. A. Katkova, A. S. Mikherdov, M. A. Kinzhalov, A. S. Novikov, A. A. Zolotarev, V. P. Boyarskiy, V. Yu. Kukushkin. Chem. Eur. J., 2019, 25, 8590–8598.
DOI: 10.1002/chem.201901187 -
Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent···Complex Halogen Bonding. M. A. Kinzhalov, M. V. Kashina, A. S. Mikherdov, E. A. Mozheeva, A. S. Novikov, A. S. Smirnov, D. M. Ivanov, M. A. Kryukova, A. Yu. Ivanov, S. N. Smirnov, V. Yu. Kukushkin, K. V. Luzyanin. Angew. Chem. Int. Ed., 2018, 57, 12785–12789.
DOI: 10.1002/anie.201807642 -
Halides Held by Bifurcated Chalcogen–Hydrogen Bonds. Effect of µ(S,N–H)Cl Contacts on Dimerization of Cl(carbene)PdII Species. A. S. Mikherdov, A. S. Novikov, M. A. Kinzhalov, V. P. Boyarskiy, G. L. Starova, A. Yu. Ivanov, V. Yu. Kukushkin. Inorg. Chem., 2018, 57, 3420–3433.
DOI: 10.1021/acs.inorgchem.8b00190 -
Difference in Energy between Two Distinct Types of Chalcogen Bonds Drives Regioisomerization of Binuclear (Diaminocarbene)PdII Complexes. A. S. Mikherdov, M. A. Kinzhalov, A. S. Novikov, V. P. Boyarskiy, I. A. Boyarskaya, D. V. Dar’in, G. L. Starova, V. Yu. Kukushkin. J. Am. Chem. Soc., 2016, 138, 14129-14137.
DOI: 10.1021/jacs.6b09133
関連する研究記事
業績一覧
2023年
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A Steric-Repulsion-Driven Clutch Stack of Triaryltriazines: Correlated Molecular Rotations and a Thermoresponsive Gearshift in the Crystalline Solid
, R. Kitsu, N. Hammyo, A. Sato-Tomita, M. Mizuno, A. S. Mikherdov, M. Tsitsvero, A. Lyalin, T. Taketsugu, H. Ito, J. Am. Chem. Soc., 2023, 145, 50, 27512-27520
DOI: 10.1021/jacs.3c08909