About the Research
Research Theme
Molecular Rotors in Solid State with Photo-Functions
Keyword
Molecular rotor, Metal-complex, Photo-luminescene in solid-state
Research History
See my CV.
Representative Research Achievements
- Anisotropic Thermal Expansion as the Source of Macroscopic and Molecular Scale Motion in Phosphorescent Amphidynamic Crystals
M. Jin, S. Yamamoto, T. Seki, H. Ito, M. A. Garcia-Garibay, Angew. Chem. Int. Ed., 2019, 58, 18003 – 18010
DOI: 10.1002/anie.201909048 - Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of 1,4-bis[tri-(p-fluorophenyl)phosphane-gold(I)-ethynyl]benzene
M. Jin, T. J. Chung, T. Seki, H Ito, M. A. Garcia-Garibay, J. Am. Chem. Soc., 2017, 139, 18115 – 18121
DOI: 10.1021/jacs.7b11316 - Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color
M. Jin, T. Sumitani, H. Sato, T. Seki, H. Ito, J. Am. Chem. Soc., 2018, 140, 2875 – 2879
DOI: 10.1021/jacs.7b12455 - Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions between Chiral and Non-Chiral Space Groups
M. Jin, T. Seki, H. Ito, J. Am. Chem. Soc., 2017, 139, 7452 – 7455
DOI: 10.1021/jacs.7b04073
Related Research
Publications
2023
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Multidynamic Crystalline Molecular Rotors Comprising an N-Heterocyclic Carbene Binuclear Au(I) Complex Bearing Multiple Rotators
, S. Matsuura, H. Yamamoto, M. Mizuno, H. Ito, European Journal of Organic Chemistry, 2023, 26, 12,
DOI: 10.1002/ejoc.202201468
2022
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Solid-State Luminescence of Au(I) Complexes with External Stimuli-Responsive Properties
, H. Ito, Journal of Photochemistry and Photobiology C-Photochemistry Reviews, 2022, 51,
DOI: 10.1016/j.jphotochemrev.2021.100478
2021
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Distinct Fold-Mode Formation of Crystalline Cu(I) Helical Coordination Polymers with Alternation of the Solid-State Emission Using Shape of the Counter Anions
, R. Ando, H. Ito, Inorg. Chem., 2021, 61, 3-9
DOI: 10.1021/acs.inorgchem.1c02725
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Charge-Transfer Crystal with Segregated Packing Structure Constructed with Hexaarylbenzene and Tetracyanoquinodimethane
, M. Jin, H. Ito, Crystengcomm, 2021, 23, 5564-5568
DOI: 10.1039/d1ce00726b
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Introduction of a Luminophore into Generic Polymers via Mechanoradical Coupling with a Prefluorescent Reagent
, N. Toyoshima, D. Miura, J. L. Jiang, S. Maeda, M. Jin, H. Ito, Angew. Chem., Int. Ed., 2021, 60, 16003-16008
DOI: 10.1002/anie.202105381
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Encapsulating N-Heterocyclic Carbene Binuclear Transition-Metal Complexes as a New Platform for Molecular Rotation in Crystalline Solid-State
, R. Ando, M. J. Jellen, M. A. Garcia-Garibay, H. Ito, J. Am. Chem. Soc., 2021, 143, 1144-1153
DOI: 10.1021/jacs.0c11981
2019
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Anisotropic Thermal Expansion as the Source of Macroscopic and Molecular Scale Motion in Phosphorescent Amphidynamic Crystals
, S. Yamamoto, T. Seki, H. Ito, MA. Garcia-Garibay, Angew. Chem., Int. Ed., 2019, 58, 18003-18010
DOI: 10.1002/anie.201909048