レイスロナルドラゾ

thumbnail image
レイスロナルドラゾ
連絡先

rlreyes atmark icredd.hokudai.ac.jp

澤村 正也 グループ
主任研究者
教員
博士研究員
研究協力者

研究紹介

研究テーマ

Catalytic Asymmetric C–H activation/functionalization enabling the elaboration and diversification of molecules

キーワード

Asymmetric Synthesis, Organometallic Catalysis, C–H Activation, Borylation
研究概要

I have been working on the development of transition-metal catalyzed asymmetric C–H bond activation/functionalization to enable the construction of compounds with three-dimensional structural diversity. In particular, I am greatly interested in the elaboration of transformative synthetic strategies that circumvent challenges in the activation of C(sp3)–H bonds. Inspired by the efficiency of enzymes in enabling such challenging transformations, my ultimate dream is to create highly competent synthetic catalysts that can facilitate similar reactivities in a sustainable, green, and atom-economical manner.

経歴

経歴書を参照願います。

代表的な研究成果

  • Asymmetric Synthesis of -Aminoboronates via Rhodium-Catalyzed Enantioselective C(sp3)–H Borylation
    R. L. Reyes, M. Sato, T. Iwai, and M. Sawamura, J. Am. Chem. Soc., 2020, 142, 589–597
    DOI: 10.1021/jacs.9b12013
  • Iridium-catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds
    R. L. Reyes, T. Iwai, S. Maeda, and M. Sawamura, J. Am. Chem. Soc., 2019, 141, 6817–6821
    DOI:  10.1021/jacs.9b01952
  • Enantioselective Rh- or Ir-Catalyzed Directed C(sp3)–H Borylation with Phosphoramidite Chiral Ligands
    R. L. Reyes, T. Harada, T. Taniguchi, K. Monde, T. Iwai, and M. Sawamura,
    Chemistry Letters, 2017, 46, 1747–1750
    DOI: 10.1246/cl.170853

関連する研究記事