研究紹介
研究テーマ
有機ホウ素化合物やC-H結合活性化を用いる触媒的有機合成反応・不斉 触媒反応の開発
キーワード
有機合成化学、有機金属化学、C-H結合活性化、有機ホウ素化学
研究概要
遷移金属触媒によるC-C結合形成反応において重要なトランスメタル化反応を研究しています。最近、トランスメタル化反応に高い活性を示す環状トリオールボレート塩を開発しました。 また、有機ボロン酸の付加反応のためのトランスメタル化反応から始まる新しい触媒反応を開発しました。さらに、新しいキラル触媒を開発し高エナンチオ選択的反応の開発をしています。 現在、C-H結合活性化反応を利用した不斉触媒反応の研究をしています。
経歴
経歴書を参照願います。
代表的な研究成果
- Cationic Iridium/S-Me-BIPAM-Catalyzed Direct Asymmetric Intermolecular Hydroarylation of Bicycloalkenes
T. Shirai, Y. Yamamoto, Angew. Chem. Int. Ed., 2015, 54, 9894−9897
DOI: 10.1002/anie.201504563 - Cationic Ir/Me-BIPAM-Catalyzed Asymmetric Intramolecular Direct Hydroarylation of α-Keto Amides
T. Shirai, H. Ito, Y. Yamamoto, Angew. Chem. Int. Ed., 2014, 53, 2658−2661
DOI: 10.1002/anie.201400147 - Me-BIPAM for Enantioselective Ruthenium(II)-catalyzed Arylation of Aldehydes with Arylboronic Acids
Y. Yamamoto, K. Kurihara, N. Miyaura, Angew. Chem., Int. Ed., 2009, 48, 4414−4416
DOI: 10.1002/Anie.200901395 - Cyclic Triolborates: Air- and Water-stable Ate Complexes of Organoboronic Acids
Y. Yamamoto, M. Takizawa, X. Q. Yu, N. Miyaura, Angew. Chem. Int. Ed., 2008, 47, 928−931
DOI: 10.1002/Anie.200704162 - Rhodium- or Iridium-catalyzed tans-Hydroboration of Terminal Alkynes, Giving (Z)-1-Alkenylboron Compounds
T. Ohmura, Y. Yamamoto, N. Miyaura, J. Am. Chem. Soc., 2000, 122, 4990−4991
DOI: 10.1021/ja0002823
業績一覧
2022年
-
Cationic Iridium/Chiral Bidentate Phosphoramidite Catalyzed Asymmetric Hydroarylation
, Y. Yamamoto, Synthesis-Stuttgart, 2022, 54, 4764-4772
DOI: 10.1055/a-1683-9455
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Cationic Iridium-Catalyzed Asymmetric Decarbonylative Aryl Addition of Aromatic Aldehydes to Bicyclic Alkenes
, Y. Morimoto, K. Kanemoto, Y. Yamamoto, T. Shirai, Chem. Eur. J., 2022, 28,
DOI: 10.1002/chem.202104347
2021年
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Suzuki-Miyaura Catalyst-Transfer Polycondensation of Triolborate-Type Carbazole Monomers
, M. Ashiya, T. Yamamoto, K. Tajima, Y. Yamamoto, T. Isono, T. Satoh, Polymers, 2021, 13,
DOI: 10.3390/polym13234168
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DIASTEREO- AND ENANTIOSELECTIVE INTRAMOLECULAR 1,6-C-H INSERTION REACTION OF DIARYLDIAZOMETHANES CATALYZED BY CHIRAL DIRHODIUM(II) CARBOXYLATES
, Y. Kondo, R. Namie, Y. Natori, K. Takeda, H. Nambu, M. Anada, Y. Yamamoto, S. Hashimoto, Heterocycles, 2021, 103, 1078-1098
DOI: 10.3987/com-20-s(k)61
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Synthesis of Boron Nitride Nanotubes Using Plasma-Assisted CVD Catalyzed by Cu Nanoparticles and Oxygen
, I. Yamane, S. Nodo, R. Ota, T. Yanase, T. Nagahama, Y. Yamamoto, T. Shimada, Nanomaterials, 2021, 11,
DOI: 10.3390/nano11030651
2020年
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Suzuki-Miyaura Catalyst-Transfer Polycondensation of Triolborate-Type Fluorene Monomer: Toward Rapid Access to Polyfluorene-Containing Block and Graft Copolymers from Various Macroinitiators
, K. Fujiwara, D. H. Jiang, T. Yamamoto, K. Tajima, Y. Yamamoto, T. Isono, T. Satoh, Polym. Chem., 2020, 11, 6832-6839
DOI: 10.1039/d0py01127d
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Cationic Iridium/Chiral Bisphosphine-Catalyzed Enantioselective Hydroacylation of Ketones
, T. Iwasaki, K. Kanemoto, Y. Yamamoto, Chem. Asian J., 2020, 15, 1858-1862
DOI: 10.1002/asia.202000386
2019年
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Decarbonylation through Aldehydic C-H Bond Cleavage by a Cationic Iridium Catalyst
, K. Sugimoto, M. Iwasaki, R. Sumida, H. Fujita, Y. Yamamoto, Synlett, 2019, 30, 972-976
DOI: 10.1055/s-0037-1611802
2018年
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Iridium-Catalyzed Direct Asymmetric Alkylation of Aniline Derivatives Using 2-Norbornene
, T. Okamoto, Y. Yamamoto, Asian J. Org. Chem., 2018, 7, 1054-1056
DOI: 10.1002/ajoc.201800185
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Asymmetric Hydroarylation of Unsaturated Bond via C-H Functionalization by Cationic Iridium/bisphosphoramidite Catalyst
, Y. Yamamoto, Yuki Gosei Kagaku Kyokaishi, 2018, 76, 604-614
DOI: 10.5059/yukigoseikyokaishi.76.604
2017年
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Synthesis of Acylborons by Ozonolysis of Alkenylboronates: Preparation of an Enantioenriched Amino-Acid Acylboronate
, T. Ikeda, R. Takahashi, I. Sasaki, Y. Ogasawara, T. Dairi, N. Kato, Y. Yamamoto, JW. Bode, H. Ito, Angew. Chem., Int. Ed., 2017, 56, 13847-13851
DOI: 10.1002/anie.201707933
2016年
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Rhodium-Catalyzed Enantioselective Arylation of Aliphatic Imines
, T. Shirai, Y. Yamamoto, Chem. Eur. J., 2016, 22, 7739-7742
DOI: 10.1002/chem.201601246
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Stereoselective Construction of Spiro-Fused Tricyclic Frameworks by Sequential Reaction of Enynes, Imines, and Diazoalkenes with Rh(I) and Rh(II) Catalysts
, Y. Oonishi, Y. Yamamoto, K. Nakajima, Y. Sato, J. Org. Chem., 2016, 81, 7847-7854
DOI: 10.1021/acs.joc.6b01502
2015年
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Enantioselective Addition of Arylboronic Acids to Methyl 2-Formylbenzoates by Using a Ruthenium/Me-BIPAM Catalyst for Synthesis of Chiral 3-Aryl-Isobenzofuranones
, Y. Yamamoto, Org. Biomol. Chem., 2015, 13, 10874-10880
DOI: 10.1039/C5OB01661D
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Ruthenium-Me-BIPAM-Catalyzed Addition Reaction of Aryl-Boronic Acids to Benzofuran-2,3-Diones for the Enantioselective Synthesis of 3-Aryl-3-Hydroxybenzofuran-2-Ones
, Y. Yamamoto, Tetrahedron: Asymmetry, 2015, 26, 1430-1435
DOI: 10.1016/j.tetasy.2015.10.010
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Cationic Iridium/S-Me-BIPAM-Catalyzed Direct Asymmetric Intermolecular Hydroarylation of Bicycloalkenes
, Y. Yamamoto, Angew. Chem., Int. Ed., 2015, 54, 9894-9897
DOI: 10.1002/anie.201504563
2014年
-
Cationic Ir/Me-BIPAM-Catalyzed Asymmetric Intramolecular Direct Hydroarylation of α-Keto Amides
, H. Ito, Y. Yamamoto, Angew. Chem., Int. Ed., 2014, 53, 2658-2661
DOI: 10.1002/anie.201400147
2013年
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Tetrabutylammonium 2-Pyridyltriolborate Salts for Suzuki-Miyaura Cross-Coupling Reactions with Aryl Chlorides
, M. Takizawa, J. Sugai, H. Ito, Y. Yamamoto, Org. Lett., 2013, 15, 4308-4311
DOI: 10.1021/ol402268g
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Asymmetric Addition Reactions of Organoboron Compounds Using Bidentate Phosphoramidite Ligand
, Yuki Gosei Kagaku Kyokaishi, 2013, 71, 716-727
DOI: 10.5059/yukigoseikyokaishi.71.716
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Cross-Coupling Reaction with Lithium Methyltriolborate
, K. Ikizakura, H. Ito, N. Miyaura, Molecules, 2013, 18, 430-439
DOI: 10.3390/molecules18010430
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An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Ketones
, K. Kurihara, Y. Takahashi, N. Miyaura, Molecules, 2013, 18, 14-26
DOI: 10.3390/molecules18010014
2012年
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Cyclic Triolborate Salts, Novel Reagent for Organic Synthesis
, Heterocycles, 2012, 85, 799-819
DOI: 10.3987/REV-12-728
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Me-BIPAM for the Synthesis of Optically Active 3-Aryl-3-Hydroxy-2-Oxindoles by Ruthenium-Catalyzed Addition of Arylboronic Acids to Isatins
, M. Yohda, T. Shirai, H. Ito, N. Miyaura, Chem. Asian J., 2012, 7, 2446-2449
DOI: 10.1002/asia.201200481
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Asymmetric Addition of Arylboronic Acids to Glyoxylate Catalyzed by a Ruthenium/Me-BIPAM Complex
, T. Shirai, N. Miyaura, Chem. Commun., 2012, 48, 2803-2805
DOI: 10.1039/c2cc17339e
2011年
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Cross-Coupling Reactions of Organoboranes: An Easy Method for C-C Bonding
, Y. Yamamoto, Chem. Lett., 2011, 40, 894-901
DOI: 10.1246/cl.2011.894
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Direct Conversion of Pinacol Arylboronic Esters to Aryl Triolborates
, S. Kiyomura, Y. Yamamoto, N. Miyaura, Chem. Lett., 2011, 40, 702-704
DOI: 10.1246/cl.2011.702
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Double-Coupling of Dibromo Arenes with Aryltriolborates for Synthesis of Diaryl-Substituted Planar Frameworks
, Y. Yamamoto, N. Miyaura, Tetrahedron, 2011, 67, 6804-6811
DOI: 10.1016/j.tet.2011.06.083
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Synthesis of Tetra-Ortho-Substituted Biaryls Using Aryltriolborates
, Y. Yamamoto, N. Miyaura, Synlett, 2011, , 1769-1773
DOI: 10.1055/s-0030-1260932
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Rhodium-Catalyzed 1,4-Addition of Lithium 2-Furyltriolborates to Unsaturated Ketones and Esters for Enantioselective Synthesis of γ-Oxo-Carboxylic Acids by Oxidation of the Furyl Ring with Ozone
, T. Shirai, Y. Yamamoto, N. Miyaura, Chem. Asian J., 2011, 6, 932-937
DOI: 10.1002/asia.201000589
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Synthesis of Lithium 2-Pyridyltriolborate and Its Cross-Coupling Reaction with Aryl Halides
, J. Sugai, M. Takizawa, N. Miyaura, Org. Synth., 2011, 88, 79-86
DOI: 10.1002/0471264229.os088.08
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Ru/Me-BIPAM-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes and α-Keto Esters
, T. Shirai, M. Watanabe, K. Kurihara, N. Miyaura, Molecules, 2011, 16, 5020-5034
DOI: 10.3390/molecules16065020
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Enantioselective Synthesis of Arylglycine Derivatives by Asymmetric Addition of Arylboronic Acids to Imines
, Y. Takahashi, K. Kurihara, N. Miyaura, Aust. J. Chem., 2011, 64, 1447-1453
DOI: 10.1071/CH11225
2010年
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Palladium-Catalyzed Cross-Coupling Reaction of Heteroaryltriolborates with Aryl Halides for Synthesis of Biaryls
, M. Takizawa, XQ. Yu, N. Miyaura, Heterocycles, 2010, 80, 359-368
DOI: 10.3987/COM-09-S(S)30
2009年
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A Chiral Bidentate Phosphoramidite (Me-BIPAM) for Rh-Catalyzed Asymmetric Hydrogenation of α-Dehydroamino Esters, Enamides, and Dimethyl Itaconate
, Y. Yamamoto, N. Miyaura, Tetrahedron Lett., 2009, 50, 3158-3160
DOI: 10.1016/j.tetlet.2008.12.086
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An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to N-Sulfonylarylaldimines
, Y. Yamamoto, N. Miyaura, Adv. Synth. Catal., 2009, 351, 260-270
DOI: 10.1002/adsc.200800631
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Rhodium-Catalyzed Asymmetric 1,4-Addition of Heteroaryl Cyclic Triolborate to α,β-Unsaturated Carbonyl Compounds
, Y. Yamamoto, N. Miyaura, Synlett, 2009, , 994-998
DOI: 10.1055/s-0028-1088198
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Effect of Ambient Gas and Temperature on Crystallization of Boron Nitride Spheres Prepared by Vapor Phase Pyrolysis of Ammonia Borane
, Y. Yamamoto, H. Kiyono, S. Shimada, J. Am. Ceram. Soc., 2009, 92, 787-792
DOI: 10.1111/j.1551-2916.2009.02941.x
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Me-Bipam for Enantioselective Ruthenium(II)-Catalyzed Arylation of Aldehydes with Arylboronic Acids
, K. Kurihara, N. Miyaura, Angew. Chem., Int. Ed., 2009, 48, 4414-4416
DOI: 10.1002/anie.200901395
2008年
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Stepwise Palladium-Catalyzed 1,4-Addition of Arylboronic Acids to Enones and Regioselective Baeyer-Villiger Oxidation for Enantioselective Synthesis of β-Diaryl Esters and (+)-(R)-Tolterodine
, T. Nishikata, Y. Yamamoto, N. Miyaura, Bull. Chem. Soc. Jpn., 2008, 81, 1019-1025
DOI: 10.1246/bcsj.81.1019
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Practical Synthesis of Pinacolborane for One-Pot Synthesis of Unsymmetrical Biaryls via Aromatic C-H Borylation-Cross-Coupling Sequence
, Y. Nobuta, J. Umeda, Y. Yamamoto, T. Ishiyama, N. Miyaura, Tetrahedron, 2008, 64, 4967-4971
DOI: 10.1016/j.tet.2008.03.102
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Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Esters Catalyzed by Dicationic Palladium(II)-Chiraphos Complex for Short-Step Synthesis of SmithKline Beecham's Endothelin Receptor Antagonist
, S. Kiyomura, Y. Yamamoto, N. Miyaura, Synlett, 2008, , 2487-2490
DOI: 10.1055/s-2008-1078259
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Aryl Triolborates: Novel Reagent for Copper-Catalyzed N-Arylation of Amines, Anilines, and Imidazoles
, Y. Yamamoto, N. Miyaura, Chem. Asian J., 2008, 3, 1517-1522
DOI: 10.1002/asia.200800135
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Preparation and Characterization of BN Nanotubes with Controllable Sizes by Template-Aided Synthesis
, S. Shimada, H. Kiyono, Y. Yamamoto, Mater. Res. Soc. Symp. Proc., 2008, 1081E, No pp. given
DOI: 10.1557/proc-1081-p05-22
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Preparation of h-BN Nano-Tubes, -Bamboos, and -Fibers from Borazine Oligomer with Alumina Porous Template
, S. Shimada, Y. Yamamoto, N. Miyaura, Mater. Res. Bull., 2008, 43, 251-256
DOI: 10.1016/j.materresbull.2007.03.020
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Highly Ordered Boron Nitride Nanotube Arrays with Controllable Texture from Ammonia Borane by Template-Aided Vapor-Phase Pyrolysis
, Y. Yamamoto, H. Kiyono, S. Shimada, C., Journal of Nanomaterials, 2008, ,
DOI: 10.1155/2008/606283
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Cyclic Triol Borates: Air- and Water-Stable Ate Complexes of Organoboronic Acids
, M. Takizawa, Y. Xq, N. Miyaura, Angew. Chem., Int. Ed., 2008, 47, 928-931
DOI: 10.1002/anie.200704162
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Metal-Catalyzed Reactions of Organoboron Compounds in Organic Syntheses
, N. Miyaura, Yuki Gosei Kagaku Kyokaishi, 2008, 66, 194-204
DOI: 10.5059/yukigoseikyokaishi.66.194
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1,4-Additions of Arylboron, -Silicon, and -Bismuth Compounds to α,β-Unsaturated Carbonyl Compounds Catalyzed by Dicationic Palladium(II) Complexes
, T. Nishikata, N. Miyaura, Pure Appl. Chem., 2008, 80, 807-817
DOI: 10.1351/pac200880050807
2007年
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Enantioselective 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds Catalyzed by Rhodium(I)-Chiral Phosphoramidite Complexes
, N. Sugishita, K. Oshita, D. Piao, Y. Yamamoto, N. Miyaura, J. Organomet. Chem., 2007, 692, 428-435
DOI: 10.1016/j.jorganchem.2006.04.042
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Tandem Conjugate Addition-Aldol Cyclization to Give Optically Active 1-Aryl-1H-Indenes via Asymmetric Pd2+-Catalyzed 1,4-Addition of Aryl-Boronic Acids
, Y. Kobayashi, K. Kobayshi, Y. Yamamoto, N. Miyaura, Synlett, 2007, , 3055-3057
DOI: 10.1055/s-2007-990964
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Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated N-Acylamides Catalyzed by Dicationic Palladium(II)-(S,S)-Chiraphos Complex
, Y. Yamamoto, N. Miyaura, Chem. Lett., 2007, 36, 1442-1443
DOI: 10.1246/cl.2007.1442
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Palladium(II)-Catalyzed 1,4-Addition of Arylboronic Acids to β-Arylenals for Enantioselective Syntheses of 3,3-Diarylalkanals: A Short Synthesis of (+)-(R)-CDP 840
, Y. Yamamoto, N. Miyaura, Tetrahedron Lett., 2007, 48, 4007-4010
DOI: 10.1016/j.tetlet.2007.04.038
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Palladium(II)-Catalyzed 1,4-Addition of Arylboronic Acids to β-Arylenones for Enantioselective Synthesis of 4-Aryl-4H-Chromenes
, Y. Yamamoto, N. Miyaura, Adv. Synth. Catal., 2007, 349, 1759-1764
DOI: 10.1002/adsc.200600622
2006年
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1,4-Addition of Arylboronic Acids to β-Aryl-α,β-Unsaturated Ketones and Esters Catalyzed by a Rhodium(I)-Chiraphos Complex for Catalytic and Enantioselective Synthesis of Selective Endothelin A Receptor Antagonists
, T. Mase, T. Nishikata, T. Iyama, H. Tachikawa, Y. Kobayashi, Y. Yamamoto, N. Miyaura, Tetrahedron, 2006, 62, 9610-9621
DOI: 10.1016/j.tet.2006.07.075
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Synthesis of B-Trisubstituted Borazines via the Rhodium-Catalyzed Hydroboration of Alkenes with N,N',N''-Trimethyl or N,N',N''-Triethylborazine
, K. Miyamoto, J. Umeda, Y. Nakatani, T. Yamamoto, N. Miyaura, J. Organomet. Chem., 2006, 691, 4909-4917
DOI: 10.1016/j.jorganchem.2006.08.024
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Asymmetric Cross-Coupling of Potassium 2-Butenyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)(2)/Josiphos Complex
, S. Takada, N. Miyaura, Chem. Lett., 2006, 35, 1368-1369
DOI: 10.1246/cl.2006.1368
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γ-Selective Cross-Coupling of Potassium Allyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)2/D-t-BPF Complex
, S. Takada, N. Miyaura, Chem. Lett., 2006, 35, 704-705
DOI: 10.1246/cl.2006.704
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Rhodium(I)- or Palladium(II)-Catalyzed 1,4-Additions of Organoboron, -Silicon and -Bismuth Compounds to Electron-Deficient Alkenes
, T. Nishikata, N. Miyaura, Yuki Gosei Kagaku Kyokaishi, 2006, 64, 1112-1121
DOI: 10.5059/yukigoseikyokaishi.64.1112
2005年
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Asymmetric 1,4-Addition of Potassium Aryltrifluoroborates [ArBF3]K to Enones Catalyzed by Dicationic Palladium(II) Complexes
, Y. Yamamoto, N. Miyaura, Chem. Lett., 2005, 34, 720-721
DOI: 10.1246/cl.2005.720
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Chiral Bis-Phosphoramidites Based on Linked-BINOL for Rhodium-Catalyzed 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds
, K. Kurihara, N. Sugishita, K. Oshita, D. Piao, N. Miyaura, Chem. Lett., 2005, 34, 1224-1225
DOI: 10.1246/cl.2005.1224
2004年
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Asymmetric 1,4-Addition of Triarylbismuths to Enones Catalyzed by Dicationic Palladium(II) Complexes
, Y. Yamamoto, N. Miyaura, Chem. Commun., 2004, , 1822-1823
DOI: 10.1039/b407272c
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Iridium-Catalyzed Hydroboration of Alkenes with Pinacolborane
, R. Fujikawa, T. Umemoto, N. Miyaura, Tetrahedron, 2004, 60, 10695-10700
DOI: 10.1016/j.tet.2004.09.014
2003年
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1,4-Addition of Arylsiloxanes to Enones Catalyzed by Dicationic Palladium(II) Complexes in Aqueous Media
, Y. Yamamoto, N. Miyaura, Chem. Lett., 2003, 32, 752-753
DOI: 10.1246/cl.2003.752
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Conjugate Addition of Aryl Boronic Acids to Enones Catalyzed by Cationic Palladium(II)-Phosphane Complexes
, Y. Yamamoto, N. Miyaura, Angew. Chem., Int. Ed., 2003, 42, 2768-2770
DOI: 10.1002/anie.200350888
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Intramolecular Allylboration of γ-(ω-Formylalkoxy)allylboronates for Syntheses of Trans- or Cis-2-(ethenyl)tetrahydropyran-3-Ol and 2-(ethenyl)oxepan-3-Ol
, K. Kurihara, A. Yamada, M. Takahashi, Y. Takahashi, N. Miyaura, Tetrahedron, 2003, 59, 537-542
DOI: 10.1016/S0040-4020(02)01557-0
2002年
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Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-Propenyl]boronic Acids to Enones
, M. Fujita, N. Miyaura, Synlett, 2002, , 767-768
DOI: 10.1055/s-2002-25371
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Synthesis of Pinacol Allylic Boronic Esters via Olefin Cross-Metathesis between Pinacol Allylboronate and Terminal or Internal Alkenes
, M. Takahashi, N. Miyaura, Synlett, 2002, , 128-130
DOI: 10.1055/s-2002-19356
2000年
-
Rhodium- or Iridium-Catalyzed Trans-Hydroboration of Terminal Alkynes, Giving (Z)-1-Alkenylboron Compounds
, Y. Yamamoto, N. Miyaura, J. Am. Chem. Soc., 2000, 122, 4990-4991
DOI: 10.1021/ja0002823
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Stereoselective Isomerization of Unsymmetrical Diallyl Ethers to Allyl (E)-Vinyl Ethers by a Cationic Iridium Catalyst
, R. Fujikawa, N. Miyaura, Synth. Commun., 2000, 30, 2383-2391
DOI: 10.1080/00397910008086880
1999年
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A Regio- and Stereoselective Platinum(0)-Catalyzed Hydroboration of Allenes Controlled by Phosphine Ligands
, R. Fujikawa, A. Yamada, N. Miyaura, Chem. Lett., 1999, , 1069-1070
DOI: 10.1246/cl.1999.1069
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Synthesis of Chiral Esters of (E)-3-(Silyloxy)-2-Propenylboronic Acid via the Iridium-Catalyzed Isomerization of the Double Bond
, T. Miyairi, T. Ohmura, N. Miyaura, J. Org. Chem., 1999, 64, 296-298
DOI: 10.1021/JO9814288
1998年
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A Stereoselective Isomerization of Allyl Silyl Ethers to (E)- or (Z)-Silyl Enol Ethers Using Cationic Iridium Complexes
, Y. Yamamoto, N. Miyaura, Chem. Commun. (Cambridge), 1998, , 1337-1338
DOI: 10.1039/a802760i
1997年
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Enantioselective Synthesis of Ipsenol and Ipsdienol Using a (2-Bromoallyl)borane Derivative
, S. Hara, A. Suzuki, Synth. Commun., 1997, 27, 1029-1036
DOI: 10.1080/00397919708003047
1996年
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Enantioselective Synthesis of Quaternary Carbon in Homoallylic Alcohols by the Reaction of Tartrate Ester Derivatives of 3,3-Disubstituted Allylborane with Aldehydes
, S. Hara, A. Suzuki, Synlett, 1996, , 883-884
DOI: 10.1055/s-1996-5628
1994年
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The Asymmetric Synthesis of 2-Bromohomoallylic Alcohols Using the Tartrate Ester of (2-Bromoallyl)boronic Acid Prepared by Bromoboration Reaction of Allene
, Y. Yamamoto, A. Fujita, A. Suzuki, Synlett, 1994, , 639-40
DOI: 10.1055/s-1994-22956
1993年
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A Stereoselective Synthesis of 3,3-Disubstituted Allylborane Derivatives Using Haloboration Reaction and Their Application to the Diastereospecific Synthesis of Homoallylic Alcohols Having Quaternary Carbon
, Y. Yamamoto, S. Hara, A. Suzuki, Tetrahedron Lett., 1993, 34, 7071-4
DOI: 10.1016/S0040-4039(00)61601-5