YAMAMOTO, Yasunori

thumbnail image
YAMAMOTO, Yasunori
Related Website
Contact

administrative_director atmark icredd.hokudai.ac.jp yasuyama@eng.hokudai.ac.jp

About the Research

Research Theme

Development of catalytic organic reactions or catalytic asymmetric reactions using organoboron compounds and C-H bond activation reaction

Keyword

Synthetic organic chemistry, Organometallic chemistry, C-H Bond activation reaction, Organoboron chemistry
Research Outline

My main research topics including transmetalation between organometallic reagents and transition metals is a fundamental process involved in metal-catalyzed C-C bond-forming reactions. It is the first step in metal-catalyzed addition reaction and the second step in the metal-catalyzed cross-coupling reactions. In this field, I have developed novel cyclic triolborate salts which have high reactivity for transmetalation to transition metal complexes. Moreover, I recently developed a new catalytic cycle starting from transmetalation for the addition reaction of organoboronic acids and their enantioselective versions using chiral catalysts. These researches led to a development of bidentate bisphosphoramidite (Me-BIPAM) as a new chiral ligand which resulted in high enantioselectivities.

Research History

See my CV.

Representative Research Achievements

  • Cationic Iridium/S-Me-BIPAM-Catalyzed Direct Asymmetric Intermolecular Hydroarylation of Bicycloalkenes
    T. Shirai, Y. Yamamoto, Angew. Chem. Int. Ed., 2015, 54, 9894−9897
    DOI: 10.1002/anie.201504563
  • Cationic Ir/Me-BIPAM-Catalyzed Asymmetric Intramolecular Direct Hydroarylation of α-Keto Amides
    T. Shirai, H. Ito, Y. Yamamoto, Angew. Chem. Int. Ed., 2014, 53, 2658−2661
    DOI: 10.1002/anie.201400147
  • Me-BIPAM for Enantioselective Ruthenium(II)-catalyzed Arylation of Aldehydes with Arylboronic Acids
    Y. Yamamoto, K. Kurihara, N. Miyaura, Angew. Chem., Int. Ed., 2009, 48, 4414−4416
    DOI: 10.1002/Anie.200901395
  • Cyclic Triolborates: Air- and Water-stable Ate Complexes of Organoboronic Acids
    Y. Yamamoto, M. Takizawa, X. Q. Yu, N. Miyaura, Angew. Chem. Int. Ed., 2008, 47, 928−931
    DOI: 10.1002/Anie.200704162
  • Rhodium- or Iridium-catalyzed tans-Hydroboration of Terminal Alkynes, Giving (Z)-1-Alkenylboron Compounds
    T. Ohmura, Y. Yamamoto, N. Miyaura, J. Am. Chem. Soc., 2000, 122, 4990−4991
    DOI: 10.1021/ja0002823

Publications

2019

  • Decarbonylation through Aldehydic C-H Bond Cleavage by a Cationic Iridium Catalyst
    T. Shirai, K. Sugimoto, M. Iwasaki, R. Sumida, H. Fujita, Y. Yamamoto, Synlett, 2019, 30, 972-976
    DOI: 10.1055/s-0037-1611802

2018

  • Iridium-Catalyzed Direct Asymmetric Alkylation of Aniline Derivatives Using 2-Norbornene
    T. Shirai, T. Okamoto, Y. Yamamoto, Asian J. Org. Chem., 2018, 7, 1054-1056
    DOI: 10.1002/ajoc.201800185
  • Asymmetric Hydroarylation of Unsaturated Bond via C-H Functionalization by Cationic Iridium/bisphosphoramidite Catalyst
    T. Shirai, Y. Yamamoto, Yuki Gosei Kagaku Kyokaishi, 2018, 76, 604-614
    DOI: 10.5059/yukigoseikyokaishi.76.604

2017

  • Synthesis of Acylborons by Ozonolysis of Alkenylboronates: Preparation of an Enantioenriched Amino-Acid Acylboronate
    J. Taguchi, T. Ikeda, R. Takahashi, I. Sasaki, Y. Ogasawara, T. Dairi, N. Kato, Y. Yamamoto, JW. Bode, H. Ito, Angew. Chem., Int. Ed., 2017, 56, 13847-13851
    DOI: 10.1002/anie.201707933

2016

  • Rhodium-Catalyzed Enantioselective Arylation of Aliphatic Imines
    N. Kato, T. Shirai, Y. Yamamoto, Chem. Eur. J., 2016, 22, 7739-7742
    DOI: 10.1002/chem.201601246
  • Stereoselective Construction of Spiro-Fused Tricyclic Frameworks by Sequential Reaction of Enynes, Imines, and Diazoalkenes with Rh(I) and Rh(II) Catalysts
    Y. Hato, Y. Oonishi, Y. Yamamoto, K. Nakajima, Y. Sato, J. Org. Chem., 2016, 81, 7847-7854
    DOI: 10.1021/acs.joc.6b01502

2015

  • Enantioselective Addition of Arylboronic Acids to Methyl 2-Formylbenzoates by Using a Ruthenium/Me-BIPAM Catalyst for Synthesis of Chiral 3-Aryl-Isobenzofuranones
    M. Yohda, Y. Yamamoto, Org. Biomol. Chem., 2015, 13, 10874-10880
    DOI: 10.1039/C5OB01661D
  • Ruthenium-Me-BIPAM-Catalyzed Addition Reaction of Aryl-Boronic Acids to Benzofuran-2,3-Diones for the Enantioselective Synthesis of 3-Aryl-3-Hydroxybenzofuran-2-Ones
    M. Yohda, Y. Yamamoto, Tetrahedron: Asymmetry, 2015, 26, 1430-1435
    DOI: 10.1016/j.tetasy.2015.10.010
  • Cationic Iridium/S-Me-BIPAM-Catalyzed Direct Asymmetric Intermolecular Hydroarylation of Bicycloalkenes
    T. Shirai, Y. Yamamoto, Angew. Chem., Int. Ed., 2015, 54, 9894-9897
    DOI: 10.1002/anie.201504563
  • Scope and Mechanistic Studies of the Cationic Ir/Me-BIPAM-Catalyzed Asymmetric Intramolecular Direct Hydroarylation Reaction
    T. Shirai, Y. Yamamoto, Organometallics, 2015, 34, 3459-3463
    DOI: 10.1021/om501260w

2014

  • Cationic Ir/Me-BIPAM-Catalyzed Asymmetric Intramolecular Direct Hydroarylation of α-Keto Amides
    T. Shirai, H. Ito, Y. Yamamoto, Angew. Chem., Int. Ed., 2014, 53, 2658-2661
    DOI: 10.1002/anie.201400147

2013

  • Tetrabutylammonium 2-Pyridyltriolborate Salts for Suzuki-Miyaura Cross-Coupling Reactions with Aryl Chlorides
    S. Sakashita, M. Takizawa, J. Sugai, H. Ito, Y. Yamamoto, Org. Lett., 2013, 15, 4308-4311
    DOI: 10.1021/ol402268g
  • Asymmetric Addition Reactions of Organoboron Compounds Using Bidentate Phosphoramidite Ligand
    Y. Yamamoto, Yuki Gosei Kagaku Kyokaishi, 2013, 71, 716-727
    DOI: 10.5059/yukigoseikyokaishi.71.716
  • Cross-Coupling Reaction with Lithium Methyltriolborate
    Y. Yamamoto, K. Ikizakura, H. Ito, N. Miyaura, Molecules, 2013, 18, 430-439
    DOI: 10.3390/molecules18010430
  • An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Ketones
    Y. Yamamoto, K. Kurihara, Y. Takahashi, N. Miyaura, Molecules, 2013, 18, 14-26
    DOI: 10.3390/molecules18010014

2012

  • Cyclic Triolborate Salts, Novel Reagent for Organic Synthesis
    Y. Yamamoto, Heterocycles, 2012, 85, 799-819
    DOI: 10.3987/REV-12-728
  • Me-BIPAM for the Synthesis of Optically Active 3-Aryl-3-Hydroxy-2-Oxindoles by Ruthenium-Catalyzed Addition of Arylboronic Acids to Isatins
    Y. Yamamoto, M. Yohda, T. Shirai, H. Ito, N. Miyaura, Chem. Asian J., 2012, 7, 2446-2449
    DOI: 10.1002/asia.201200481
  • Asymmetric Addition of Arylboronic Acids to Glyoxylate Catalyzed by a Ruthenium/Me-BIPAM Complex
    Y. Yamamoto, T. Shirai, N. Miyaura, Chem. Commun., 2012, 48, 2803-2805
    DOI: 10.1039/c2cc17339e

2011

  • Cross-Coupling Reactions of Organoboranes: An Easy Method for C-C Bonding
    A. Suzuki, Y. Yamamoto, Chem. Lett., 2011, 40, 894-901
    DOI: 10.1246/cl.2011.894
  • Direct Conversion of Pinacol Arylboronic Esters to Aryl Triolborates
    GQ. Li, S. Kiyomura, Y. Yamamoto, N. Miyaura, Chem. Lett., 2011, 40, 702-704
    DOI: 10.1246/cl.2011.702
  • Double-Coupling of Dibromo Arenes with Aryltriolborates for Synthesis of Diaryl-Substituted Planar Frameworks
    GQ. Li, Y. Yamamoto, N. Miyaura, Tetrahedron, 2011, 67, 6804-6811
    DOI: 10.1016/j.tet.2011.06.083
  • Synthesis of Tetra-Ortho-Substituted Biaryls Using Aryltriolborates
    GQ. Li, Y. Yamamoto, N. Miyaura, Synlett, 2011, , 1769-1773
    DOI: 10.1055/s-0030-1260932
  • Pd/Josiphos-Catalyzed Enantioselective α-Arylation of Silyl Ketene Acetals and Mechanistic Studies on Transmetalation and Enantioselection
    K. Kobayashi, Y. Yamamoto, N. Miyaura, Organometallics, 2011, 30, 6323-6327
    DOI: 10.1021/om200945q
  • Rhodium-Catalyzed 1,4-Addition of Lithium 2-Furyltriolborates to Unsaturated Ketones and Esters for Enantioselective Synthesis of γ-Oxo-Carboxylic Acids by Oxidation of the Furyl Ring with Ozone
    XQ. Yu, T. Shirai, Y. Yamamoto, N. Miyaura, Chem. Asian J., 2011, 6, 932-937
    DOI: 10.1002/asia.201000589
  • Synthesis of Lithium 2-Pyridyltriolborate and Its Cross-Coupling Reaction with Aryl Halides
    Y. Yamamoto, J. Sugai, M. Takizawa, N. Miyaura, Org. Synth., 2011, 88, 79-86
    DOI: 10.1002/0471264229.os088.08
  • Ru/Me-BIPAM-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes and α-Keto Esters
    Y. Yamamoto, T. Shirai, M. Watanabe, K. Kurihara, N. Miyaura, Molecules, 2011, 16, 5020-5034
    DOI: 10.3390/molecules16065020
  • Enantioselective Synthesis of Arylglycine Derivatives by Asymmetric Addition of Arylboronic Acids to Imines
    Y. Yamamoto, Y. Takahashi, K. Kurihara, N. Miyaura, Aust. J. Chem., 2011, 64, 1447-1453
    DOI: 10.1071/CH11225

2010

  • Palladium-Catalyzed Cross-Coupling Reaction of Heteroaryltriolborates with Aryl Halides for Synthesis of Biaryls
    Y. Yamamoto, M. Takizawa, XQ. Yu, N. Miyaura, Heterocycles, 2010, 80, 359-368
    DOI: 10.3987/COM-09-S(S)30
  • Cyclic Triolborates
    Y. Yamamoto, N. Miyaura, Organomet. News, 2010, , 72-77
    DOI:

2009

  • A Chiral Bidentate Phosphoramidite (Me-BIPAM) for Rh-Catalyzed Asymmetric Hydrogenation of α-Dehydroamino Esters, Enamides, and Dimethyl Itaconate
    K. Kurihara, Y. Yamamoto, N. Miyaura, Tetrahedron Lett., 2009, 50, 3158-3160
    DOI: 10.1016/j.tetlet.2008.12.086
  • An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to N-Sulfonylarylaldimines
    K. Kurihara, Y. Yamamoto, N. Miyaura, Adv. Synth. Catal., 2009, 351, 260-270
    DOI: 10.1002/adsc.200800631
  • Rhodium-Catalyzed Asymmetric 1,4-Addition of Heteroaryl Cyclic Triolborate to α,β-Unsaturated Carbonyl Compounds
    XQ. Yu, Y. Yamamoto, N. Miyaura, Synlett, 2009, , 994-998
    DOI: 10.1055/s-0028-1088198
  • Effect of Ambient Gas and Temperature on Crystallization of Boron Nitride Spheres Prepared by Vapor Phase Pyrolysis of Ammonia Borane
    YT. Wang, Y. Yamamoto, H. Kiyono, S. Shimada, J. Am. Ceram. Soc., 2009, 92, 787-792
    DOI: 10.1111/j.1551-2916.2009.02941.x
  • Me-Bipam for Enantioselective Ruthenium(II)-Catalyzed Arylation of Aldehydes with Arylboronic Acids
    Y. Yamamoto, K. Kurihara, N. Miyaura, Angew. Chem., Int. Ed., 2009, 48, 4414-4416
    DOI: 10.1002/anie.200901395
  • Metal-Catalyzed Bond-Forming Reactions of Organo-Boronic Acids
    Y. Yamamoto, N. Miyaura, Kagaku Kogyo, 2009, 60, 9-14
    DOI:
  • γ-Selective Cross-Coupling Reactions of Potassium Allyltrifluoroborates with Haloarenes Catalyzed by a Pd(0)/D-t-BPF or Pd(0)/Josiphos ((R,S)-CyPF-t-Bu) Complex: Mechanistic Studies on Transmetalation and Enantioselection
    Y. Yamamoto, S. Takada, N. Miyaura, T. Iyama, H. Tachikawa, Organometallics, 2009, 28, 152-160
    DOI: 10.1021/om800832r

2008

  • Stepwise Palladium-Catalyzed 1,4-Addition of Arylboronic Acids to Enones and Regioselective Baeyer-Villiger Oxidation for Enantioselective Synthesis of β-Diaryl Esters and (+)-(R)-Tolterodine
    K. Kobayashi, T. Nishikata, Y. Yamamoto, N. Miyaura, Bull. Chem. Soc. Jpn., 2008, 81, 1019-1025
    DOI: 10.1246/bcsj.81.1019
  • Practical Synthesis of Pinacolborane for One-Pot Synthesis of Unsymmetrical Biaryls via Aromatic C-H Borylation-Cross-Coupling Sequence
    T. Kikuchi, Y. Nobuta, J. Umeda, Y. Yamamoto, T. Ishiyama, N. Miyaura, Tetrahedron, 2008, 64, 4967-4971
    DOI: 10.1016/j.tet.2008.03.102
  • Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Esters Catalyzed by Dicationic Palladium(II)-Chiraphos Complex for Short-Step Synthesis of SmithKline Beecham's Endothelin Receptor Antagonist
    T. Nishikata, S. Kiyomura, Y. Yamamoto, N. Miyaura, Synlett, 2008, , 2487-2490
    DOI: 10.1055/s-2008-1078259
  • Aryl Triolborates: Novel Reagent for Copper-Catalyzed N-Arylation of Amines, Anilines, and Imidazoles
    XQ. Yu, Y. Yamamoto, N. Miyaura, Chem. Asian J., 2008, 3, 1517-1522
    DOI: 10.1002/asia.200800135
  • Preparation and Characterization of BN Nanotubes with Controllable Sizes by Template-Aided Synthesis
    YT. Wang, S. Shimada, H. Kiyono, Y. Yamamoto, Mater. Res. Soc. Symp. Proc., 2008, 1081E, No pp. given
    DOI: 10.1557/proc-1081-p05-22
  • Preparation of h-BN Nano-Tubes, -Bamboos, and -Fibers from Borazine Oligomer with Alumina Porous Template
    YT. Wang, S. Shimada, Y. Yamamoto, N. Miyaura, Mater. Res. Bull., 2008, 43, 251-256
    DOI: 10.1016/j.materresbull.2007.03.020
  • Highly Ordered Boron Nitride Nanotube Arrays with Controllable Texture from Ammonia Borane by Template-Aided Vapor-Phase Pyrolysis
    YT. Wang, Y. Yamamoto, H. Kiyono, S. Shimada, C., Journal of Nanomaterials, 2008, ,
    DOI: 10.1155/2008/606283
  • Cyclic Triol Borates: Air- and Water-Stable Ate Complexes of Organoboronic Acids
    Y. Yamamoto, M. Takizawa, Y. Xq, N. Miyaura, Angew. Chem., Int. Ed., 2008, 47, 928-931
    DOI: 10.1002/anie.200704162
  • Metal-Catalyzed Reactions of Organoboron Compounds in Organic Syntheses
    Y. Yamamoto, N. Miyaura, Yuki Gosei Kagaku Kyokaishi, 2008, 66, 194-204
    DOI: 10.5059/yukigoseikyokaishi.66.194
  • 1,4-Additions of Arylboron, -Silicon, and -Bismuth Compounds to α,β-Unsaturated Carbonyl Compounds Catalyzed by Dicationic Palladium(II) Complexes
    Y. Yamamoto, T. Nishikata, N. Miyaura, Pure Appl. Chem., 2008, 80, 807-817
    DOI: 10.1351/pac200880050807

2007

  • Enantioselective 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds Catalyzed by Rhodium(I)-Chiral Phosphoramidite Complexes
    K. Kurihara, N. Sugishita, K. Oshita, D. Piao, Y. Yamamoto, N. Miyaura, J. Organomet. Chem., 2007, 692, 428-435
    DOI: 10.1016/j.jorganchem.2006.04.042
  • Cross-Coupling Reactions Using Allyltrifluoroborate
    N. Miyaura, Y. Yamamoto, Organomet. News, 2007, , 16-21
    DOI:
  • Tandem Conjugate Addition-Aldol Cyclization to Give Optically Active 1-Aryl-1H-Indenes via Asymmetric Pd2+-Catalyzed 1,4-Addition of Aryl-Boronic Acids
    T. Nishikata, Y. Kobayashi, K. Kobayshi, Y. Yamamoto, N. Miyaura, Synlett, 2007, , 3055-3057
    DOI: 10.1055/s-2007-990964
  • Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated N-Acylamides Catalyzed by Dicationic Palladium(II)-(S,S)-Chiraphos Complex
    T. Nishikata, Y. Yamamoto, N. Miyaura, Chem. Lett., 2007, 36, 1442-1443
    DOI: 10.1246/cl.2007.1442
  • Palladium(II)-Catalyzed 1,4-Addition of Arylboronic Acids to β-Arylenals for Enantioselective Syntheses of 3,3-Diarylalkanals: A Short Synthesis of (+)-(R)-CDP 840
    T. Nishikata, Y. Yamamoto, N. Miyaura, Tetrahedron Lett., 2007, 48, 4007-4010
    DOI: 10.1016/j.tetlet.2007.04.038
  • Palladium(II)-Catalyzed 1,4-Addition of Arylboronic Acids to β-Arylenones for Enantioselective Synthesis of 4-Aryl-4H-Chromenes
    T. Nishikata, Y. Yamamoto, N. Miyaura, Adv. Synth. Catal., 2007, 349, 1759-1764
    DOI: 10.1002/adsc.200600622

2006

  • 1,4-Addition of Arylboronic Acids to β-Aryl-α,β-Unsaturated Ketones and Esters Catalyzed by a Rhodium(I)-Chiraphos Complex for Catalytic and Enantioselective Synthesis of Selective Endothelin A Receptor Antagonists
    T. Itoh, T. Mase, T. Nishikata, T. Iyama, H. Tachikawa, Y. Kobayashi, Y. Yamamoto, N. Miyaura, Tetrahedron, 2006, 62, 9610-9621
    DOI: 10.1016/j.tet.2006.07.075
  • Synthesis of B-Trisubstituted Borazines via the Rhodium-Catalyzed Hydroboration of Alkenes with N,N',N''-Trimethyl or N,N',N''-Triethylborazine
    Y. Yamamoto, K. Miyamoto, J. Umeda, Y. Nakatani, T. Yamamoto, N. Miyaura, J. Organomet. Chem., 2006, 691, 4909-4917
    DOI: 10.1016/j.jorganchem.2006.08.024
  • Asymmetric Cross-Coupling of Potassium 2-Butenyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)(2)/Josiphos Complex
    Y. Yamamoto, S. Takada, N. Miyaura, Chem. Lett., 2006, 35, 1368-1369
    DOI: 10.1246/cl.2006.1368
  • γ-Selective Cross-Coupling of Potassium Allyltrifluoroborates with Aryl and 1-Alkenyl Bromides Catalyzed by a Pd(OAc)2/D-t-BPF Complex
    Y. Yamamoto, S. Takada, N. Miyaura, Chem. Lett., 2006, 35, 704-705
    DOI: 10.1246/cl.2006.704
  • Rhodium(I)- or Palladium(II)-Catalyzed 1,4-Additions of Organoboron, -Silicon and -Bismuth Compounds to Electron-Deficient Alkenes
    Y. Yamamoto, T. Nishikata, N. Miyaura, Yuki Gosei Kagaku Kyokaishi, 2006, 64, 1112-1121
    DOI: 10.5059/yukigoseikyokaishi.64.1112

2005

  • Enantioselective 1,4-Addition of Ar3Bi, [ArBF3]K, and ArSiF3 to Enones Catalyzed by a Dicationic Palladium(II)-Chiraphos or -Dipamp Complex
    T. Nishikata, Y. Yamamoto, ID. Gridnev, N. Miyaura, Organometallics, 2005, 24, 5025-5032
    DOI: 10.1021/om050678t
  • Asymmetric 1,4-Addition of Potassium Aryltrifluoroborates [ArBF3]K to Enones Catalyzed by Dicationic Palladium(II) Complexes
    T. Nishikata, Y. Yamamoto, N. Miyaura, Chem. Lett., 2005, 34, 720-721
    DOI: 10.1246/cl.2005.720
  • Chiral Bis-Phosphoramidites Based on Linked-BINOL for Rhodium-Catalyzed 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds
    Y. Yamamoto, K. Kurihara, N. Sugishita, K. Oshita, D. Piao, N. Miyaura, Chem. Lett., 2005, 34, 1224-1225
    DOI: 10.1246/cl.2005.1224

2004

  • 1,4-Addition of Arylboronic Acids and Arylsiloxanes to α,β-Unsaturated Carbonyl Compounds via Transmetalation to Dicationic Palladium(II) Complexes
    T. Nishikata, Y. Yamamoto, N. Miyaura, Organometallics, 2004, 23, 4317-4324
    DOI: 10.1021/om0498044
  • Asymmetric 1,4-Addition of Triarylbismuths to Enones Catalyzed by Dicationic Palladium(II) Complexes
    T. Nishikata, Y. Yamamoto, N. Miyaura, Chem. Commun., 2004, , 1822-1823
    DOI: 10.1039/b407272c
  • Iridium-Catalyzed Hydroboration of Alkenes with Pinacolborane
    Y. Yamamoto, R. Fujikawa, T. Umemoto, N. Miyaura, Tetrahedron, 2004, 60, 10695-10700
    DOI: 10.1016/j.tet.2004.09.014

2003

  • 1,4-Addition of Arylsiloxanes to Enones Catalyzed by Dicationic Palladium(II) Complexes in Aqueous Media
    T. Nishikata, Y. Yamamoto, N. Miyaura, Chem. Lett., 2003, 32, 752-753
    DOI: 10.1246/cl.2003.752
  • Conjugate Addition of Aryl Boronic Acids to Enones Catalyzed by Cationic Palladium(II)-Phosphane Complexes
    T. Nishikata, Y. Yamamoto, N. Miyaura, Angew. Chem., Int. Ed., 2003, 42, 2768-2770
    DOI: 10.1002/anie.200350888
  • Intramolecular Allylboration of γ-(ω-Formylalkoxy)allylboronates for Syntheses of Trans- or Cis-2-(ethenyl)tetrahydropyran-3-Ol and 2-(ethenyl)oxepan-3-Ol
    Y. Yamamoto, K. Kurihara, A. Yamada, M. Takahashi, Y. Takahashi, N. Miyaura, Tetrahedron, 2003, 59, 537-542
    DOI: 10.1016/S0040-4020(02)01557-0

2002

  • Inter- and Intramolecular Additions of 1-Alkenylboronic Acids or Esters to Aldehydes and Ketones Catalyzed by Rhodium(I) Complexes in Basic, Aqueous Solutions
    A. Takezawa, K. Yamaguchi, T. Ohmura, Y. Yamamoto, N. Miyaura, Synlett, 2002, , 1733-1735
    DOI:
  • Recent Progress in P-C Bond-Forming Reactions Using Transition Metal Catalysts
    Y. Yamamoto, Organomet. News, 2002, , 52
    DOI:
  • Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-Propenyl]boronic Acids to Enones
    Y. Yamamoto, M. Fujita, N. Miyaura, Synlett, 2002, , 767-768
    DOI: 10.1055/s-2002-25371
  • Synthesis of Pinacol Allylic Boronic Esters via Olefin Cross-Metathesis between Pinacol Allylboronate and Terminal or Internal Alkenes
    Y. Yamamoto, M. Takahashi, N. Miyaura, Synlett, 2002, , 128-130
    DOI: 10.1055/s-2002-19356

2000

  • Iridium-Catalyzed Dimerization of Terminal Alkynes to (E)-Enynes, (Z)-Enynes, or 1,2,3-Butatrienes
    T. Ohmura, S. Yorozuya, Y. Yamamoto, N. Miyaura, Organometallics, 2000, 19, 365-367
    DOI: 10.1021/om990912d
  • Rhodium- or Iridium-Catalyzed Trans-Hydroboration of Terminal Alkynes, Giving (Z)-1-Alkenylboron Compounds
    T. Ohmura, Y. Yamamoto, N. Miyaura, J. Am. Chem. Soc., 2000, 122, 4990-4991
    DOI: 10.1021/ja0002823
  • Stereoselective Isomerization of Unsymmetrical Diallyl Ethers to Allyl (E)-Vinyl Ethers by a Cationic Iridium Catalyst
    Y. Yamamoto, R. Fujikawa, N. Miyaura, Synth. Commun., 2000, 30, 2383-2391
    DOI: 10.1080/00397910008086880

1999

  • Stereoselective Synthesis of Silyl Enol Ethers via the Iridium-Catalyzed Isomerization of Allyl Silyl Ethers
    T. Ohmura, Y. Yamamoto, N. Miyaura, Organometallics, 1999, 18, 413-416
    DOI: 10.1021/OM980794E
  • A Regio- and Stereoselective Platinum(0)-Catalyzed Hydroboration of Allenes Controlled by Phosphine Ligands
    Y. Yamamoto, R. Fujikawa, A. Yamada, N. Miyaura, Chem. Lett., 1999, , 1069-1070
    DOI: 10.1246/cl.1999.1069
  • Synthesis of Chiral Esters of (E)-3-(Silyloxy)-2-Propenylboronic Acid via the Iridium-Catalyzed Isomerization of the Double Bond
    Y. Yamamoto, T. Miyairi, T. Ohmura, N. Miyaura, J. Org. Chem., 1999, 64, 296-298
    DOI: 10.1021/JO9814288

1998

  • A Stereoselective Isomerization of Allyl Silyl Ethers to (E)- or (Z)-Silyl Enol Ethers Using Cationic Iridium Complexes
    T. Ohmura, Y. Yamamoto, N. Miyaura, Chem. Commun. (Cambridge), 1998, , 1337-1338
    DOI: 10.1039/a802760i

1997

  • Enantioselective Synthesis of Ipsenol and Ipsdienol Using a (2-Bromoallyl)borane Derivative
    Y. Yamamoto, S. Hara, A. Suzuki, Synth. Commun., 1997, 27, 1029-1036
    DOI: 10.1080/00397919708003047

1996

  • Enantioselective Synthesis of Quaternary Carbon in Homoallylic Alcohols by the Reaction of Tartrate Ester Derivatives of 3,3-Disubstituted Allylborane with Aldehydes
    Y. Yamamoto, S. Hara, A. Suzuki, Synlett, 1996, , 883-884
    DOI: 10.1055/s-1996-5628

1994

  • The Asymmetric Synthesis of 2-Bromohomoallylic Alcohols Using the Tartrate Ester of (2-Bromoallyl)boronic Acid Prepared by Bromoboration Reaction of Allene
    S. Hara, Y. Yamamoto, A. Fujita, A. Suzuki, Synlett, 1994, , 639-40
    DOI: 10.1055/s-1994-22956

1993

  • A Stereoselective Synthesis of 3,3-Disubstituted Allylborane Derivatives Using Haloboration Reaction and Their Application to the Diastereospecific Synthesis of Homoallylic Alcohols Having Quaternary Carbon
    M. Sato, Y. Yamamoto, S. Hara, A. Suzuki, Tetrahedron Lett., 1993, 34, 7071-4
    DOI: 10.1016/S0040-4039(00)61601-5