About the Research
Photochemistry, Data Science, Fluorine Chemistry
We are trying to recycle greenhouse gases such fluoroform and utlizing them as cheap feedstocks to synthesis useful fluorinated organic componds. Besides, we are also pursuing C-F bond functionalization using photochemistry.
Representative Research Achievements
- FLP-Catalyzed Monoselective C–F Functionalization in Polyfluorocarbons at Geminal or Distal Sites.
Gupta, R., Mandal, D., Jaiswal, A. K., & Young, R. D. Organic Letters, 2021, 23(5), 1915–1920.
- Frustrated Lewis-Pair-Meditated Selective Single Fluoride Substitution in Trifluoromethyl Groups.
Mandal, D., Gupta, R., Jaiswal, A. K., & Young, R. D. Journal of the American Chemical Society, 2020, 142(5), 2572–2578.
- Nucleophilic Substitution of Aliphatic Fluorides via Pseudohalide Intermediates.
Jaiswal, A. K., Prasad, P. K., & Young, R. D. Chemistry – A European Journal, 2019, 25(25), 6290–6294.
- Aluminum-Catalyzed Cross-Coupling of Silylalkynes with Aliphatic C–F Bonds.
Jaiswal, A. K., Goh, K. K. K., Sung, S., & Young, R. D. Organic Letters, 2017, 19(7), 1934–1937.