JAISWAL, Amit Kumar

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JAISWAL, Amit Kumar
Postdoctoral Fellow
Affiliated until Jan 31, 2025
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Contact

akjaiswal atmark icredd.hokudai.ac.jp

HUANG, Dennis Chung-Yang Group
Junior PI
Postdoctoral Fellows

About the Research

Research Theme

Organic Chemistry

Keyword

Photochemistry, Data Science, Fluorine Chemistry

Research Outline

We are trying to recycle greenhouse gases such fluoroform and utlizing them as cheap feedstocks to synthesis useful fluorinated organic componds. Besides, we are also pursuing C-F bond functionalization using photochemistry.

Representative Research Achievements

  • FLP-Catalyzed Monoselective C–F Functionalization in Polyfluorocarbons at Geminal or Distal Sites.
    Gupta, R., Mandal, D., Jaiswal, A. K., & Young, R. D. Organic Letters, 2021, 23(5), 1915–1920.
    DOI: 10.1021/acs.orglett.1c00346
  • Frustrated Lewis-Pair-Meditated Selective Single Fluoride Substitution in Trifluoromethyl Groups.
    Mandal, D., Gupta, R., Jaiswal, A. K., & Young, R. D. Journal of the American Chemical Society, 2020, 142(5), 2572–2578.
    DOI: 10.1021/jacs.9b12167
  • Nucleophilic Substitution of Aliphatic Fluorides via Pseudohalide Intermediates.
    Jaiswal, A. K., Prasad, P. K., & Young, R. D. Chemistry – A European Journal, 2019, 25(25), 6290–6294.
    DOI: 10.1002/chem.201806272
  • Aluminum-Catalyzed Cross-Coupling of Silylalkynes with Aliphatic C–F Bonds.
    Jaiswal, A. K., Goh, K. K. K., Sung, S., & Young, R. D. Organic Letters, 2017, 19(7), 1934–1937.
    DOI: 10.1021/acs.orglett.7b00712

Related Research

Publications

2024

  • Mechanistic Exploration of N-Heterocyclic Carbene Boranes as the Hydrogen Atom Transfer Reagent in Selective Hydrodefluorination Reactions
    A. Jaiswal, B. Skjelstad, S. Maeda, D. Huang, Acs Catalysis, 2024, 14, 17547–17555
    DOI: 10.1021/acscatal.4c05092
  • Accessing a Diverse Set of Functional Red-Light Photoswitches by Selective Copper-Catalyzed Indigo N-Arylation
    A. Jaiswal, P. Saha, J. Jiang, K. Suzuki, A. Jasny, B. Schmidt, S. Maeda, S. Hecht, C. Huang, J. Am. Chem. Soc., 2024, 146, 31, 21367-21376
    DOI: 10.1021/jacs.4c03543