TANAKA III, Kosaku

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TANAKA III, Kosaku
Specially Appointed Assistant Professor
Mita Group (Maeda-ERATO)

About the Research

Research Theme

Synthetic organic chemistry, development of new chemical reactions

Keyword

Development of new chemical reactions, ketyl radical, photoexcited palladium

Research History

Please see my CV.

Representative Research Achievements

  • Ketyl Radical Generation by Photoexcited Palladium and Development of Organopalladium-Type Reactions
    K. Tanaka III. ACS Catal., 2024, 14, 5269–5274.
    DOI: 10.1021/acscatal.4c00510
  • Synthesis of N-Aryl Isoxazolidines by Photo-Promoted N-Selective Arylation of Oximes and Cyclization Using Hypervalent Iodine Reagents and Copper Catalyst
    K. Tanaka III, M. Yoshida, A. Yamamoto, Y. Hashimoto, N. Morita, O. Tamura. Adv. Synth. Catal., 2023, 365, 1419–1424.
    DOI: 10.1002/adsc.202300110
  • Electrophilic C3−H Alkenylation of 2,6-Dialkoxypyridine Derivatives via Pd(II)/Tl(III) Reaction System
    T. Yamada, K. Tanaka III, Y. Hashimoto, N. Morita, O. Tamura. Adv. Synth. Catal., 2023, 365, 3138–3148.
    DOI: 10.1002/adsc.202300650
  • Directing-Group-Free Palladium-Catalyzed C–H Arylation of Aldoxime Using Oxime’s Umpolung Properties
    K. Tanaka III, Y. Hashimoto, N. Morita, O. Tamura. Org. Lett., 2022, 24, 8954–8958.
    DOI: 10.1021/acs.orglett.2c03387
  • Enantioselective total synthesis of (+)-rubrobramide, (+)-talaramide A, and (−)-berkeleyamide D by a skeletal diversification strategy
    K. Tanaka III, K. Kobayashi, H. Kogen. Chem. Commun., 2021, 57, 9780–9783.
    DOI: 10.1039/D1CC04290D

Publications

2024

  • Photoredox-Catalyst-Free Carboxylation of Unactivated Alkenes in DMSO: Synthesis of Polycyclic Indole Derivatives and Aliphatic Acids
    S. Debbarma, H. Hayashi, Y. Ueno, W. Kanna, K. Tanaka, III, T. Mita, Org. Lett., 2024, ,
    DOI: 10.1021/acs.orglett.4c04051
  • Hetero Cope-Type Hydroamination of Hetero-Allenes with Oximes Having Olefin Moieties Leading to Nitrones, Causing Intramolecular Cycloaddition
    Y. Ide, N. Matsuda, M. Osada, A. Yamamoto, K. III. Tanaka, Y. Hashimoto, N. Morita, O. Tamura, J. Org. Chem., 2024, 89, 18, 12973–12981
    DOI: 10.1021/acs.joc.4c00986
  • Highly Efficient and Thermally Durable Luminescence of 1D Eu3+ Coordination Polymers with Arsenic Bridging Ligands
    H. Shimoji, Y. Aoyama, K. Inage, M. Nakamura, T. Yanagihara, K. Yuhara, Y. Kitagawa, Y. Hasegawa, S. Ito, K. Tanaka, H. Imoto, K. Naka, Chem. Eur. J., 2024, ,
    DOI: 10.1002/chem.202400615