研究紹介
研究テーマ
AFIR法に基づくメカノケミカル反応に関する研究、理論先導反応設計
キーワード
理論化学, ラジカル化学, 有機金属化学, メカノケミカル反応
研究概要
経歴書をご覧ください。
代表的な研究成果
- Gao, P.; Jiang, J.; Fukuzawa, Y.; Maeda, S.; Kubota, K.; Ito, H. Direct arylation of alkyl fluorides using in situ mechanochemically generated calcium-based heavy Grignard reagents. RSC Mechanochem. 2024, Advance Article.
DOI: 10.1039/D4MR00067F - Shiratori, Y.; Jiang, J.; Kubota, K.; Maeda, S.; Ito, H. Ring Expansion of Cyclic Boronates via Oxyboration of Arynes. J. Am. Chem. Soc. 2024, 146, 1765-1770.
DOI: 10.1021/jacs.3c11851 - Kubota, K.; Jiang, J.; Kamakura, Y.; Hisazumi, R.; Endo, T.; Miura, D.; Kubo, S.; Maeda, S.; Ito, H. Using Mechanochemistry to Activate Commodity Plastics as Initiators for Radical Chain Reactions of Small Organic Molecules. J. Am. Chem. Soc. 2024, 146, 1062–1070.
DOI: 10.1021/jacs.3c12049 - Zheng, Y.; Jiang, J.; Jin, M.; Miura, D.; Lu, F.; Kubota, K.; Nakajima, T.; Maeda, S.; Ito, H.; Gong, J. P. In Situ and Real-Time Visualization of Mechanochemical Damage in Double-Network Hydrogels by Prefluorescent Probe via Oxygen-Relayed Radical Trapping. J. Am. Chem. Soc. 2023, 145, 7376–7389.
DOI: 10.1021/jacs.2c13764 - Jiang, J.; Yu, J. Q.; Morokuma, K. Mechanism and Stereoselectivity of Directed C(sp3)–H Activation and Arylation Catalyzed by Pd(II) with Pyridine Ligand and Trifluoroacetate: A Computational Study. ACS Catal. 2015, 5, 3648-3661.
DOI: 10.1021/cs501626n
業績一覧
2024年
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Mechanochemical Generation of Aryl Barium Nucleophiles from Unactivated Barium Metal
, S. Kawamura, J. Jiang, S. Maeda, H. Ito, Chem. Sci., 2024, Issue 42,
DOI: 10.1039/d4sc05361c
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Accessing a Diverse Set of Functional Red-Light Photoswitches by Selective Copper-Catalyzed Indigo N-Arylation
, P. Saha, J. Jiang, K. Suzuki, A. Jasny, B. Schmidt, S. Maeda, S. Hecht, C. Huang, J. Am. Chem. Soc., 2024, 146, 31, 21367-21376
DOI: 10.1021/jacs.4c03543