JIANG, Julong

JIANG, Julong

Junior PI, Associate Professor

jjiang.theochem atmark icredd.hokudai.ac.jp

Research on Mechanochemical Reactions using AFIR method, Theory-guided Design of Reactions

Theoretical Chemistry, Radical Chemistry, Organometallics, Mechanochemistry

See my CV.

Gao, P.; Jiang, J.; Fukuzawa, Y.; Maeda, S.; Kubota, K.; Ito, H. Direct arylation of alkyl fluorides using in situ mechanochemically generated calcium-based heavy Grignard reagents. RSC Mechanochem. 2024, Advance Article.
DOI: 10.1039/D4MR00067F
Shiratori, Y.; Jiang, J.; Kubota, K.; Maeda, S.; Ito, H. Ring Expansion of Cyclic Boronates via Oxyboration of Arynes. J. Am. Chem. Soc. 2024, 146, 1765-1770.
DOI: 10.1021/jacs.3c11851
Kubota, K.; Jiang, J.; Kamakura, Y.; Hisazumi, R.; Endo, T.; Miura, D.; Kubo, S.; Maeda, S.; Ito, H. Using Mechanochemistry to Activate Commodity Plastics as Initiators for Radical Chain Reactions of Small Organic Molecules. J. Am. Chem. Soc. 2024, 146, 1062–1070.
DOI: 10.1021/jacs.3c12049
Zheng, Y.; Jiang, J.; Jin, M.; Miura, D.; Lu, F.; Kubota, K.; Nakajima, T.; Maeda, S.; Ito, H.; Gong, J. P. In Situ and Real-Time Visualization of Mechanochemical Damage in Double-Network Hydrogels by Prefluorescent Probe via Oxygen-Relayed Radical Trapping. J. Am. Chem. Soc. 2023, 145, 7376–7389.
DOI: 10.1021/jacs.2c13764
Jiang, J.; Yu, J. Q.; Morokuma, K. Mechanism and Stereoselectivity of Directed C(sp³)–H Activation and Arylation Catalyzed by Pd(II) with Pyridine Ligand and Trifluoroacetate: A Computational Study. ACS Catal. 2015, 5, 3648-3661.
DOI: 10.1021/cs501626n

Breaking the Immiscibility Barrier: A Mechanochemical Approach to Enable the Direct Glycosylation of Native Sugars with Hydrophobic Aliphatic Alcohols
K. Kubota, Y. Kamakura, T. Takeda, J. Jiang, Y. Manabe, K. Fukase, H. Ito, J. Am. Chem. Soc., 2026, ,
DOI: 10.1021/jacs.6c04094
Rh-Catalyzed Chemodivergent Parallel Kinetic Resolution and Desymmetrization of Enynes and Dienynes with Acrylamides
S. Hamada, J. Jiang, Y. Sato, T. Yamazaki, S. Maeda, K. Tanaka, Angew. Chem., Int. Ed., 2026, ,
DOI: 10.1002/anie.9965825
Using Mechanochemistry to Activate Poly(vinyl chloride) as a Mechanotunable Brønsted-Acid-Releasing Reagent for Organic Synthesis
K. Kubota, R. Hisazumi, K. Jana, J. Jiang, T. Endo, S. Maeda, H. Ito, J. Am. Chem. Soc., 2026, 148, 1, 1953-1962
DOI: 10.1021/jacs.5c20376

Computational Exploration of Polymer Mechanochemistry: Quantitation of Activation Force and Systematic Discovery of Reaction Sites by the Extended Artificial Force-Induced Reaction Method
J. Jiang, K. Kubota, Y. Harabuchi, M. Jin, Z. Wang, T. Nakajima, H. Ito, J. Gong, S. Maeda, J. Am. Chem. Soc., 2025, 147, 32502-32521
DOI: 10.1021/jacs.5c06150
"Node" Facilitated Thermostable Mechanophores for Rapid Self-Strengthening in Double Network Materials
J. Jiang, Z. Wang, R. Staub, Y. Harabuchi, A. Varnek, J. Gong, S. Maeda, Chem. Sci., 2025, 16, 14278-14285
DOI: 10.1039/d5sc00151j
A Cooperative Electron-Deficient Phosphine/olefin Ligand System for the Site-Selective Mechanochemical Suzuki-Miyaura Cross-Coupling of 2,4-Dibromoaryl Ethers
Y. Gao, J. Jiang, S. Maeda, K. Kubota, H. Ito, Chem. Sci., 2025, ,
DOI: 10.1039/d5sc01669j
Introducing Steric Bulk Into Silylboranes: Enhanced Bench Stability and Novel Chemical Reactivity
R. Takahashi, J. Jiang, S. Maeda, H. Ito, Angew. Chem., Int. Ed., 2025, ,
DOI: 10.1002/anie.202506194

Mechanochemical Generation of Aryl Barium Nucleophiles from Unactivated Barium Metal
K. Kubota, S. Kawamura, J. Jiang, S. Maeda, H. Ito, Chem. Sci., 2024, Issue 42,
DOI: 10.1039/d4sc05361c
Accessing a Diverse Set of Functional Red-Light Photoswitches by Selective Copper-Catalyzed Indigo N-Arylation
A. Jaiswal, P. Saha, J. Jiang, K. Suzuki, A. Jasny, B. Schmidt, S. Maeda, S. Hecht, C. Huang, J. Am. Chem. Soc., 2024, 146, 31, 21367-21376
DOI: 10.1021/jacs.4c03543