About the Research
Research Theme
Organic synthesis
Keyword
Mechanochemistry, silicon chemistry, main-group inorganic chemistry
Research Outline
See my CV.
Representative Research Achievements
- Fluorination/dearomatization of C6F5 groups: An FLP route to an electrophilic borane and noncoordinating anions
H. Kim, D. Mandal, J. K. J. Ng, Z.-w. Qu, S. Grimme, D. W. Stephan, Chem. Eur. J. 2024, 30, e202401776
DOI: 10.1002/chem.202401776 - Addition and N=N bond cleavage of diazo-compounds by phosphino-phosphenium cations
H. Kim, A. Lough, Z.-w. Qu, S. Grimme, D. W. Stephan. Chem. Commun. 2024, 60, 1031–1034
DOI: 10.1039/D3CC05728C - Phosphino-phosphinations: Frustrated Lewis pair reactions of phosphino-phosphonium cations with alkynes. H. Kim, Z.-w. Qu, S. Grimme, N. Al-Zuhaika, D. W. Stephan
Angew. Chem. Int. Ed. 2023, 62, e202312587
DOI: 10.1002/anie.202312587 - Reactive FLP-alkyne addition products: A route to anionic and zwitterionic phosphines
H. Kim, D. W. Stephan. Dalton Trans. 2023, 52, 5023–5027
DOI: 10.1039/D3DT00607G - Synthesis of α-δ disubstituted tetraphosphates and terminally-functionalized nucleoside pentaphosphates
S. M. Shepard, H. Kim, Q. X. Bang, N. Alhokbany, C. C. Cummins. J. Am. Chem. Soc. 2021, 143, 463–470
DOI: 10.1021/jacs.0c11884