About the Research
Research Theme
Discovery of new reaction using boron active species
Keyword
Boron, robotic synthesis, computational chemistry
Research Outline
I am trying to discover a new reaction based on the electron deficiency of boron and low electronegativity. Furthermore, I also aim to speed up reaction discovery by combining robotic synthesizer and computational chemistry.
Representative Research Achievements
- Reactivity of Highly Lewis-Acidic Diborane(4) toward C≡N Triple and N=N Double Bonds: Uncatalyzed Addition and N=N Bond Cleavage.
Y. Katsuma, L. Wu, Z. Lin, S. Akiyama, M. Yamashita, Angew. Chem. Int. Ed., 2019, 58, 317-321.
DOI : 10.1002/anie.201812692 - Reactivity of A Tetra(o-tolyl)diborane(4) Dianion as Diarylboryl Anion.
S. Akiyama, K. Yamada, M. Yamashita, Angew. Chem. Int. Ed., 2019, 58, 11806-11810.
DOI : 10.1002/anie.201907400 - Copper Complexes Bearing A Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property.
S. Akiyama, S. Ikemoto, S. Muratsugu, M. Tada, M. Yamashita, Organometallics, 2020, 39, 500-504.
DOI : 10.1021/acs.organomet.0c00027 - Formation of A Dinuclear Rh(I)–/Rh(I)+ Complex Exhibiting MMCT Absorption from Dianionic Diborane(4) through C–H Bond Cleavage.
S. Akiyama, M. Yamashita, Chem. Lett., 2020, 49, 721-723.
DOI : 10.1246/cl.200182
Related Research
Publications
2023
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OSPAR: A Corpus for Extraction of Organic Synthesis Procedures with Argument Roles
, S. Akiyama, Y. Nagata, M. Yoshioka, J. Chem. Inf. Model., 2023, 63, 21, 6619-6628
DOI: 10.1021/acs.jcim.3c01449