AKIYAMA, Seiji

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AKIYAMA, Seiji
Specially Appointed Assistant Professor
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Contact

s.aki atmark icredd.hokudai.ac.jp

MAEDA, Satoshi Group
Principal Investigator
Faculty Members
Postdoctoral Fellows
Staff

About the Research

Research Theme

Discovery of new reaction using boron active species

Keyword

Boron, robotic synthesis, computational chemistry

Research Outline

I am trying to discover a new reaction based on the electron deficiency of boron and low electronegativity. Furthermore, I also aim to speed up reaction discovery by combining robotic synthesizer and computational chemistry.

Representative Research Achievements

  • Reactivity of Highly Lewis-Acidic Diborane(4) toward C≡N Triple and N=N Double Bonds: Uncatalyzed Addition and N=N Bond Cleavage.
    Y. Katsuma, L. Wu, Z. Lin, S. Akiyama, M. Yamashita, Angew. Chem. Int. Ed., 2019, 58, 317-321.
    DOI : 10.1002/anie.201812692
  • Reactivity of A Tetra(o-tolyl)diborane(4) Dianion as Diarylboryl Anion.
    S. Akiyama, K. Yamada, M. Yamashita, Angew. Chem. Int. Ed.2019, 58, 11806-11810.
    DOI : 10.1002/anie.201907400
  • Copper Complexes Bearing A Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property.
    S. Akiyama, S. Ikemoto, S. Muratsugu, M. Tada, M. Yamashita, Organometallics2020, 39, 500-504.
    DOI : 10.1021/acs.organomet.0c00027
  • Formation of A Dinuclear Rh(I)–/Rh(I)+ Complex Exhibiting MMCT Absorption from Dianionic Diborane(4) through C–H Bond Cleavage.
    S. Akiyama, M. Yamashita, Chem. Lett.2020, 49, 721-723.
    DOI : 10.1246/cl.200182

Related Research

Publications

2023

  • OSPAR: A Corpus for Extraction of Organic Synthesis Procedures with Argument Roles
    K. Machi, S. Akiyama, Y. Nagata, M. Yoshioka, J. Chem. Inf. Model., 2023, 63, 21, 6619-6628
    DOI: 10.1021/acs.jcim.3c01449