About the Research
Research Theme
Organometallic chemistry, design new chiral ligands and new chemical reactions
Keyword
Transition metal, asymmetric catalysis, SOP ligands
Research Outline
In the past, I mainly focused on the research of carbonyl chemistry, with the purpose of solving problems that were not solved by the previous ones. At the same time, I am also committed to the development of transition metal/SOP ligand catalytic systems and the design of new chiral ligands. Now I am concerned about how to synthesize chiral silicon compounds.
Representative Research Achievements
- Palladium-Catalyzed Enantioselective Thiocarbonylation of Styrenes
X. Wang, B. Wang, X. Yin, W. Yu, Y. Liao, J. Ye, M. Wang, L. Hu, J. Liao, Angew. Chem. Int. Ed., 2019, 58, 12264
DOI: 10.1002/anie.201905905 - Cu-Catalyzed SN2′ Substitution of Propargylic Phosphates with Vinylarene-Derived Chiral Nucleophiles: Synthesis of Chiral Allenes
B. Wang, X. Wang, X. Yin, W. Yu, Y. Liao, J. Ye, M. Wang, J. Liao, Org. Lett., 2019, 21, 3913
DOI: 10.1021/acs.orglett.9b00908 - Enantioselective Synthesis of Multisubstituted Allenes by Cooperative Cu/Pd-Catalyzed 1,4-Arylboration of 1,3-Enynes
Y. Liao, X. Yin, X. Wang, W. Yu, D. Fang, L. Hu, M. Wang, J. Liao, Angew. Chem. Int. Ed., 2020, 59,1176
DOI: 10.1002/anie.201912703 - Enantioselective Palladium-Catalyzed Hydrofluorination of Alkenylarenes
X. Yin, B. Chen, F. Qiu, X. Wang, Y. Liao, M. Wang, X. Lei, J. Liao, ACS Catal., 2020, 10, 1954
DOI: 10.1021/acscatal.9b05264
Publications
2023
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Stereospecific Synthesis of Silicon-Stereogenic Optically Active Silylboranes and General Synthesis of Chiral Silyl Anions
, C. Feng, J. L. Jiang, S. Maeda, K. Kubota, H. Ito, Nat. Commun., 2023, 14, 5561
DOI: 10.1038/s41467-023-41113-z