研究紹介
研究テーマ
Photochemistry and photophysics of lanthanide comlexes
キーワード
Lanthanide, emission, magneto-opitics, nanocarbon
代表的な研究成果
- Stacked nanocarbon photosensitizer for efficient blue light excited Eu(III) emission
Y. Kitagawa*, F. Suzue, T. Nakanishi, K. Fushimi, T, Seki, H. Ito, Y. Hasegawa*, Commun. Chem., 2020, 3
DOI: 10.1038/s42004-019-0251-z - The role of π-f orbital interactions in Eu(III) complexes for an effective molecular luminescent thermometer
Y. Kitagawa*, M. Kumagai, T. Nakanishi, K. Fushimi, Y. Hasegawa*, Inorg. Chem. in press, 2020
DOI: 10.1021/acs.inorgchem.9b03492 - Electronic chirality inversion of lanthanide complex induced by achiral molecules
S. Wada, Y. Kitagawa*, T. Nakanishi, M. Gon, K. Tanaka, K. Fushimi, Y. Chujo, Y. Hasegawa*, Scientific Reports, 2018, 8, 16395
DOI: 10.1038/s41598-018-34790-0 - Visible luminescent lanthanide ions and large π-conjugated ligand system shake hands
Y. Kitagawa*, R. Ohno, T. Nakanishi, K. Fushimi, Y. Hasegawa*, Phys.Chem.Chem.Phys., 2018, 18, 31012
DOI: 10.1039/C6CP06294F - Magneto-chiral dichroism of organic compounds
Y. Kitagawa, H. Segawa, K. Ishii*, Angew. Chem. Int. Ed., 2011, 50, 9133
DOI: 10.1002/anie.201101809
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業績一覧
2024年
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Quantitative Evaluation of Hydrogen Absorption by Detecting Non-Absorbed Hydrogen in Electrochemical Hydrogen Permeation Test
, S. Shoji, Y. Kitagawa, Y. Hasegawa, K. Fushimi, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 67, 1243-1247
DOI: 10.1016/j.ijhydene.2023.10.236
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Chiral Tetrakis Eu(III) Complexes with Ammonium Cations for Improved Circularly Polarized Luminescence
, R. Takizawa, Y. Kitagawa, M. Wang, M. Kobayashi, T. Taketsugu, Y. Hasegawa, Angew. Chem., Int. Ed., 2024, ,
DOI: 10.1002/anie.202405584
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Guest-Responsive Near-Infrared-Luminescent Metal-Organic Cage Organized by Porphyrin Dyes and Yb(III) Complexes
, S. Shoji, T. Nakanishi, M. Kobayashi, M. F. Wang, K. Fushimi, T. Taketsugu, Y. Kitagawa, Y. Hasegawa, Inorg. Chem., 2024, 63, 10108–10113
DOI: 10.1021/acs.inorgchem.4c01348
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Highly Efficient and Thermally Durable Luminescence of 1D Eu3+ Coordination Polymers with Arsenic Bridging Ligands
, Y. Aoyama, K. Inage, M. Nakamura, T. Yanagihara, K. Yuhara, Y. Kitagawa, Y. Hasegawa, S. Ito, K. Tanaka, H. Imoto, K. Naka, Chem. Eur. J., 2024, ,
DOI: 10.1002/chem.202400615
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Circularly Polarized Luminescence and High Photoluminescence Quantum Yields from Rigid 5,10-Dihydroindeno[2,1-a]Indene and 2,2′-Dialkoxy-1,1′-Binaphthyl Conjugates and Copolymers
, M. Tsurui, K. Itaya, N. Hamaguchi, Y. Egawa, Y. Kitagawa, Y. Hasegawa, H. Tsuji, RSC Advances, 2024, 14, 7251-7257
DOI: 10.1039/d4ra00380b
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Current Development of Lanthanide Complexes for Biomedical Applications
, Y. Kitagawa, Y. Hasegawa, Chem. Asian J., 2024, ,
DOI: 10.1002/asia.202400038
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Passive Film Formed on Si-Mn Steel in Boric Acid-Borate Buffer at 6.5
, K. Higa, A. Fujimura, S. Shoji, Y. Kitagawa, Y. Hasegawa, H. Katayama, J. Electrochem. Soc., 2024, 171(2),
DOI: 10.1149/1945-7111/ad27b7
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Structure-Changeable Luminescent Eu(III) Complex as a Human Cancer Grade Probing System for Brain Tumor Diagnosis
, M. Kono, Y. Yamaguchi, J. Islam, S. Shoji, Y. Kitagawa, K. Fushimi, S. Watanabe, G. Matsuba, A. Yamamoto, M. Tanaka, M. Tsuda, S. Tanaka, Y. Hasegawa, Scientific Reports, 2024, 14, Article number: 778
DOI: 10.1038/s41598-023-50138-9
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Rapid Synthesis of Chiral Figure-Eight Macrocycles Using a Preorganized Natural Product-Based Scaffold
, D. Ogata, M. Tsurui, S. Yoshida, S. Sato, T. Muraoka, Y. Kitagawa, Y. Hasegawa, J. Yuasa, H. Oguri, Angew. Chem., Int. Ed., 2024, ,
DOI: 10.1002/anie.202318548
2023年
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Size-Control Synthesis and Luminescence Properties of Eu(III) Coordination Particles
, K. Sasaki, S. Shoji, M. F. Wang, K. Fushimi, Y. Kitagawa, Y. Hasegawa, J. Phys. Chem. C, 2023, 127, 23785-23791
DOI: 10.1021/acs.jpcc.3c06499
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Intensive Emission of Eu(iii) β-Diketonate Complexes with Arsine Oxide Ligands
, Fujii, T., Sumida, A., Kitagawa, Y., Hasegawa, Y., Imoto, H., Naka, K., J. Mater. Chem. C, 2023, 11, 15608-15615
DOI: 10.1039/d3tc03297c
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Sandglass-Typed Single Chameleon Luminophore for Water Mapping Measurements: Intramolecular Energy Migrations in the Hydrophilic Tb(III)/Sm(III) Cluster
, Y. Konishi, M. Enokido, S. Shoji, M. F. Wang, K. Fushimi, Y. Kitagawa, Inorg. Chem., 2023, 62, 41, 16794–16800
DOI: 10.1021/acs.inorgchem.3c02219
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Investigation of the Dissolution/passivation Mechanisms on Fe-Cr Alloys in Acidic Na2SO4 Solution Using Online ICP-OES
, S. Shoji, Y. Kitagawa, Y. Hasegawa, T. Doi, K. Fushimi, Electrochimica Acta, 2023, 463,
DOI: 10.1016/j.electacta.2023.142843
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Optical Resolution of Carboxylic Acid Derivatives of Homoleptic Cyclometalated Iridium(III) Complexes via Diastereomers Formed with Chiral Auxiliaries
, K. Yokoi, Y. Yamada, M. Tsurui, Y. Kitagawa, Y. Hasegawa, D. Ogata, J. Yuasa, S. Aoki, Inorg. Chem., 2023, 62, 29, 11325-11341
DOI: 10.1021/acs.inorgchem.3c00685
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Highly Efficient Light Harvesting of a Eu(iii) Complex in a Host-Guest Film by Triplet Sensitization
, K. Goushi, Y. Kitagawa, Y. Hasegawa, C. Adachi, K. Miyata, K. Onda, Chem. Sci., 2023, ,
DOI: 10.1039/d3sc01817b
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Initiation of Sulfide Stress Cracking Using Potentiostatic Liquid-Phase Ion Gun
, H. Yanagimoto, S. Nakatsuji, S. Shoji, Y. Kitagawa, Y. Hasegawa, K. Baba, J. Electrochem. Soc., 2023, 170, 041508
DOI: 10.1149/1945-7111/accd26
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Structural Metamorphosis and Photophysical Properties of Thermostable Nano- and Microcrystalline Lanthanide Polymer with Flexible Coordination Chains
, Y. Hirai, J. Xu, T. Takeda, S. Watanabe, A. Yasumori, S. Hakamada, Y. Kitagawa, Y. Hasegawa, Science and Technology of Advanced Materials, 2023, 24, 2183711
DOI: 10.1080/14686996.2023.2183711
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Bright Lanthanide(III) Triboluminescence Despite Low Photoluminescence, and Dual Triboluminescence and Mechano-Responsive Photoluminescence
, S. Van Baaren, T. Ohmura, T. Nakanishi, T. Takeda, Y. Kitagawa, Y. Hasegawa, R. Metivier, C. Allain, Advanced Optical Materials, 2023, ,
DOI: 10.1002/adom.202203139
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Luminescent Lanthanide Complexes for Effective Oxygen-Sensing and Singlet Oxygen Generation
, T. Nakai, S. Hosoya, S. Shoji, Y. Hasegawa, ChemPlusChem, 2023, ,
DOI: 10.1002/cplu.202200445
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A Switchable System between Magnetic and Natural Circularly Polarised Luminescence via J-Aggregation Using Photosynthetic Antenna Model Compounds
, Y. Kitagawa, K. Yoshioka, K. Murata, T. Miyatake, Y. Hasegawa, K. Ishii, J. Mater. Chem. C, 2023, 11,
DOI: 10.1039/d2tc04841h
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Controlled Molecular Assemblies of Chiral Boron Dipyrromethene Derivatives for Circularly Polarized Luminescence in the Red and Near-Infrared Regions
, Y. Suzuki, M. Tsurui, Y. Kitagawa, T. Nakashima, T. Kawai, Y. Kondo, G. Matsuba, Y. Hasegawa, T. Hasobe, J. Mater. Chem. C, 2023, ,
DOI: 10.1039/d2tc05006d
2022年
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Enhanced Circularly Polarized Luminescence of Chiral Eu(iii) Coordination Polymers with Structural Strain
, Y. Kitagawa, S. Shoji, K. Fushimi, Y. Hasegawa, Dalton Trans., 2022, ,
DOI: 10.1039/d2dt03422k
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Development of a Quasi-on-Time ICP-OES for Analyzing Electrode Reaction Products
, S. Shoji, Y. Kitagawa, Y. Hasegawa, T. Doi, K. Fushimi, Electrochimica Acta, 2022, 433,
DOI: 10.1016/j.electacta.2022.141246
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Emission Properties of Eu(III) Complexes Containing Arsine and Phosphine Ligands with Annulated Structures
, Y. Kitagawa, Y. Hasegawa, H. Imoto, K. Naka, Inorg. Chem., 2022, 61, 44,, 17662–17672
DOI: 10.1021/acs.inorgchem.2c02757
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Plant Growth Acceleration Using a Transparent Eu3+-Painted UV-to-Red Conversion Film
, H. Saito, Y. Jitsuyama, K. Tomita, Q. Haoyang, Y. Sakurai, Y. Okazaki, K. Aikawa, Y. Konishi, K. Sasaki, K. Fushimi, Y. Kitagawa, T. Suzuki, Y. Hasegawa, Scientific Reports, 2022, 12,
DOI: 10.1038/s41598-022-21427-6
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Amorphous Lanthanide Complexes for Organic Luminescent Materials
, S. Shoji, Y. Kitagawa, Y. Hasegawa, Coord. Chem. Rev., 2022, 467,
DOI: 10.1016/j.ccr.2022.214607
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Effective Photosensitization in Excited-State Equilibrium: Brilliant Luminescence of Tb-III Coordination Polymers Through Ancillary Ligand Modifications
, R. Moriake, T. Akama, K. Saito, K. Aikawa, S. Shoji, K. Fushimi, M. Kobayashi, T. Taketsugu, Y. Hasegawa, ChemPlusChem, 2022, ,
DOI: 10.1002/cplu.202200151
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Preparation of Photonic Molecular Trains via Soft-Crystal Polymerization of Lanthanide Complexes
, Y. Kitagawa, S. Shoji, H. Oyama, K. Imaeda, N. Nakayama, K. Fushimi, H. Uekusa, K. Ueno, H. Goto, Y. Hasegawa, Nat. Commun., 2022, 13,
DOI: 10.1038/s41467-022-31164-z
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Luminescent Lanthanide Coordination Polymers with Transformative Energy Transfer Processes for Physical and Chemical Sensing Applications
, Y. Kitagawa, Journal of Photochemistry and Photobiology C-Photochemistry Reviews, 2022, 51,
DOI: 10.1016/j.jphotochemrev.2022.100485
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Asymmetric Lumino-Transformer: Circularly Polarized Luminescence of Chiral Eu(III) Coordination Polymer with Phase-Transition Behavior
, Y. Kitagawa, S. Shoji, H. Ohmagari, M. Hasegawa, M. Gon, K. Tanaka, M. Kobayashi, T. Taketsugu, K. Fushimi, Y. Hasegawa, J. Phys. Chem. B, 2022, 126, 3799-3807
DOI: 10.1021/acs.jpcb.2c01639
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Tribo-Excited Chemical Reaction Using an Eu-III Complex with a Stacked Anthracene Framework
, A. Naito, K. Aikawa, K. Shima, S. Shoji, K. Fushimi, Y. Hasegawa, Chem. Eur. J., 2022, 28,
DOI: 10.1002/chem.202104401
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Luminescent Eu(III)-Based Coordination Polymers for Photonic Materials
, S. Shoji, Y. Kitagawa, Chem. Lett., 2022, 51, 185-196
DOI: 10.1246/cl.210650
2021年
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In-Situ Observation of Corrosion Initiation Occurring on NaCI Nanoparticles-Deposited Carbon Steel Surfaces
, H. Okuyama, K. Ohshimizu, S. Shoji, Y. Kitagawa, Y. Hasegawa, Tetsu to Hagane-Journal of the Iron and Steel Institute of Japan, 2021, 107, 1011-1019
DOI: 10.2355/tetsutohagane.TETSU-2021-049
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Bright Red Emission with High Color Purity from Eu(iii) Complexes with Pi-Conjugated Polycyclic Aromatic Ligands and Their Sensing Applications
, M. Tsurui, Y. Hasegawa, RSC Advances, 2021, 12, 810-821
DOI: 10.1039/d1ra08233g
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Charge-Transfer Excited States of Pi- and 4f-Orbitals for Development of Luminescent Eu(iii) Complexes
, P. P. F. da Rosa, Y. Hasegawa, Dalton Trans., 2021, 50, 14978-14984
DOI: 10.1039/d1dt03019a
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Hybrid Eu-III Coordination Luminophore Standing on Two Legs on Silica Nanoparticles for Enhanced Luminescence
, Y. Kitagawa, R. Moriake, P. P. F. da Rosa, M. J. Islam, T. Yoneda, Y. Inokuma, K. Fushimi, Y. Hasegawa, Chem. Eur. J., 2021, 27, 14438-14443
DOI: 10.1002/chem.202102156
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Isopyrazole-Masked Tetraketone: Tautomerism and Functionalization for Fluorescent Metal Ligands
, Y. Manabe, C. Kasai, Y. Inaba, M. Tsurui, Y. Kitagawa, Y. Hasegawa, T. Yoneda, Y. Ide, Y. Inokuma, European Journal of Organic Chemistry, 2021, 2021, 4345-4349
DOI: 10.1002/ejoc.202100784
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Long-Lived Emission Beyond 1000 Nm: Control of Excited-State Dynamics in a Dinuclear Tb(iii)-Nd(iii) Complex
, K. Matsuda, P. P. F. da Rosa, K. Fushimi, Y. Hasegawa, Chem. Commun., 2021, 57, 8047-8050
DOI: 10.1039/d1cc03596g
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Amide-Bridged Eu(III) Coordination Polymer for Stable Luminescent Glass Material
, S. Shoji, Y. Kitagawa, K. Fushimi, Y. Hasegawa, Materials Letters, 2021, 297, 4
DOI: 10.1016/j.matlet.2021.130012
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Drastic Enhancement of Photosensitized Energy Transfer Efficiency of a Eu(III) Complex Driven by Arsenic
, Y. Kitagawa, Y. Hasegawa, H. Imoto, K. Naka, Inorg. Chem., 2021, 60, 8605-8612
DOI: 10.1021/acs.inorgchem.1c00577
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Active-Passive Transition of an Fe-6 Mass% Cr Surface in Acidic Sodium Sulfate Solutions Under a Laminar Flow Condition Evaluated by Ellipso-Microscopy and Channel Flow Electrode Method
, Y. Kitagawa, Y. Hasegawa, T. Doi, K. Fushimi, J. Electrochem. Soc., 2021, 168, 11
DOI: 10.1149/1945-7111/abfb96
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Strong Circularly Polarized Luminescence of Mixed Lanthanide Coordination Polymers with Control of 4f Electronic Structures
, Y. Kitagawa, M. Tsurui, Y. Hasegawa, Dalton Trans., 2021, 50, 5433-5436
DOI: 10.1039/d1dt00519g
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Thermo-Sensitive Eu-III Coordination Polymers with Amorphous Networks
, N. Sato, J. Hayashi, Y. Kitagawa, K. Fushimi, ChemistrySelect, 2021, 6, 2812-2816
DOI: 10.1002/slct.202100531
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Bright Sky-Blue Fluorescence with High Color Purity: Assembly of Luminescent Diphenyl-Anthracene Lutetium-Based Coordination Polymer
, A. Naito, K. Fushimi, Y. Hasegawa, RSC Advances, 2021, 11, 6604-6606
DOI: 10.1039/d0ra10795f
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Coordination Geometrical Effect on Ligand-to-Metal Charge Transfer-Dependent Energy Transfer Processes of Luminescent Eu(III) Complexes
, S. Miyazaki, H. Sakamoto, Y. Kitagawa, K. Miyata, T. Akama, M. Kobayashi, K. Fushimi, K. Onda, T. Taketsugu, Y. Hasegawa, J. Phys. Chem. A, 2021, 125, 209-217
DOI: 10.1021/acs.jpca.0c09337
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Long-Range LMCT Coupling in Eu-III Coordination Polymers for an Effective Molecular Luminescent Thermometer**
, M. Kumagai, P. P. F. da Rosa, K. Fushimi, Y. Hasegawa, Chem. Eur. J., 2021, 27, 264-269
DOI: 10.1002/chem.202002628
2020年
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Luminescent Lanthanide Complex with Seven-Coordination Geometry
, Kitagawa, Y, Hasegawa, Y, Coord. Chem. Rev., 2020, 406, 9
DOI: 10.1016/j.ccr.2019.213153
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Splitting and Reorientation of Pi-Conjugation by an Unprecedented Photo-Rearrangement Reaction
, Yoneda, T, Kitagawa, Y, Miyata, K, Hasegawa, Y, Inokuma, Y, Chem. Commun., 2020, 56, 348-351
DOI: 10.1039/c9cc09062b
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First Tribo-Excited Chemical Reaction of a Stacked Lanthanide Coordination Polymer with an in Situ Reaction Monitor
, A. Naito, K. Fushimi, Y. Hasegawa, Chem. Eur. J., 2020, ,
DOI: 10.1002/chem.202004485
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Circularly Polarized Absorption and Luminescence of Semiconductor Eu-OCN Nanocrystals in the Blue Region of the Electromagnetic Spectrum
, K. Koide, M. Tsurui, Y. Kitagawa, T. Nakanishi, Y. Doi, Y. Hinatsu, K. Fushimi, Chemphyschem, 2020, 21, 2019-2024
DOI: 10.1002/cphc.202000468
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An Europium (III) Luminophore with Pressure-Sensing Units: Effective Back Energy Transfer in Coordination Polymers with Hexadentate Porous Stable Networks
, T. Sawanobori, Y. Kitagawa, S. Shoji, K. Fushimi, Y. Nakasaka, T. Masuda, I. Hisaki, ChemPlusChem, 2020, 85, 1989-1993
DOI: 10.1002/cplu.202000513
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Chiral Lanthanide Lumino-Glass for a Circularly Polarized Light Security Device
, S. Wada, M. D. J. Islam, K. Saita, M. Gon, K. Fushimi, K. Tanaka, S. Maeda, Y. Hasegawa, Communications Chemistry, 2020, 3, 5
DOI: 10.1038/s42004-020-00366-1
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Dual Energy Transfer Pathways from an Antenna Ligand to Lanthanide Ion in Trivalent Europium Complexes with Phosphine-Oxide Bridges
, K. Miyata, H. Sakamoto, F. Suzue, Y. Kitagawa, Y. Hasegawa, K. Onda, J. Phys. Chem. A, 2020, 124, 6601-6606
DOI: 10.1021/acs.jpca.0c02224
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Dithieno 3,4-b:3',4'-d Arsole: A Novel Class of Hetero 5 Radialenes
, T. Yumura, Y. Kitagawa, Y. Hasegawa, H. Imoto, K. Naka, European Journal of Organic Chemistry, 2020, 2020, 3965-3970
DOI: 10.1002/ejoc.202000442
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Aggregation-Induced Emission of a Eu(III) Complex via Ligand-to-Metal Charge Transfer
, M. Kumagai, K. Fushimi, Y. Hasegawa, Chemical Physics Letters, 2020, 749, 4
DOI: 10.1016/j.cplett.2020.137437
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The Role of Pi-f Orbital Interactions in Eu(III) Complexes for an Effective Molecular Luminescent Thermometer
, M. Kumagai, T. Nakanishi, K. Fushimi, Y. Hasegawa, Inorg. Chem., 2020, 59, 5865-5871
DOI: 10.1021/acs.inorgchem.9b03492
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Electronic Strain Effect on Eu(III) Complexes for Enhanced Circularly Polarized Luminescence
, Y. Kitagawa, K. Fushimi, M. Gon, K. Tanaka, Y. Hasegawa, Dalton Trans., 2020, 49, 5352-5361
DOI: 10.1039/d0dt00699h
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First Demonstration of the Pi-f Orbital Interaction Depending on the Coordination Geometry in Eu(III) Luminophores
, M. Kumagai, P. P. F. da Rosa, K. Fushimi, Y. Hasegawa, Dalton Trans., 2020, 49, 3098-3101
DOI: 10.1039/d0dt00528b
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Steric and Electronic Control of Chiral Eu(III) Complexes for Effective Circularly Polarized Luminescence
, M. Tsurui, Y. Hasegawa, Acs Omega, 2020, 5, 3786-3791
DOI: 10.1021/acsomega.9b03613
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Luminescent Coordination Polymers Constructed from a Flexible, Tetradentate Diisopyrazole Ligand and Copper(I) Halides
, C. Kasai, Y. Manabe, M. Tsurui, Y. Kitagawa, Y. Hasegawa, P. Sarkar, Y. Inokuma, Chem. Asian J., 2020, 15, 601-605
DOI: 10.1002/asia.201901682
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First Aggregation-Induced Emission of a Tb(III) Luminophore Based on Modulation of Ligand-Ligand Charge Transfer Bands
, M. Kumagai, T. Nakanishi, K. Fushimi, Y. Hasegawa, Dalton Trans., 2020, 49, 2431-2436
DOI: 10.1039/d0dt00094a
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Stacked Nanocarbon Photosensitizer for Efficient Blue Light Excited Eu(III) Emission
, F. Suzue, T. Nakanishi, K. Fushimi, T. Seki, H. Ito, Y. Hasegawa, Communications Chemistry, 2020, 3, 7
DOI: 10.1038/s42004-019-0251-z
2019年
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Thermo-Sensitive Luminescence of Lanthanide Complexes, Clusters, Coordination Polymers and Metal-Organic Frameworks with Organic Photosensitizers
, Y. Kitagawa, J. Mater. Chem. C, 2019, 7, 7494-7511
DOI: 10.1039/c9tc00607a
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Near-IR Luminescent YbIII Coordination Polymers Composed of Pyrene Derivatives for Thermostable Oxygen Sensors
, T. Matsui, Y. Kitagawa, T. Nakanishi, T. Seki, H. Ito, Y. Nakasaka, T. Masuda, K. Fushimi, Chem. Eur. J., 2019, 25, 12308-12315
DOI: 10.1002/chem.201902583
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Thermal and Crystallographic Investigation of Luminescent Eu(III) Coordination Polymers with Dithiane and Dioxane Hexyl Rings
, PPF. da Rosa, Y. Kitagawa, Y. Hasegawa, Chem. Lett., 2019, 48, 1544-1546
DOI: 10.1246/cl.190752
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Lifetimes of Lanthanide(III) Triboluminescence Excited by Aerodynamic Shock Waves
, A. Kotani, H. Sakaue, Y. Kitagawa, Y. Hasegawa, J. Phys. Chem. C, 2019, 123, 27251-27256
DOI: 10.1021/acs.jpcc.9b08349