TAKANO, Hideaki

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TAKANO, Hideaki
Specially Appointed Assistant Professor
Mita Group (Maeda-ERATO)
Current affiliation:
Assistant Professor: Institute for Advanced Research, Nagoya University &
Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University (The Shinokubo group)

About the Research

Research Theme

Development of new reaction by AFIR


Synthetic organic chemistry , Development of new reaction
Research History

See my CV

Representative Research Achievements

  • Synthesis of Bicyclo[1.1.1]pentane (BCP)-Based Straight-Shaped Diphosphine Ligands
    H. Takano, H. Katsuyama, H. Hayashi, M. Harukawa, M. Tsurui, S. Shoji, Y. Hasegawa, S. Maeda, T. Mita, Angew. Chem., Int. Ed. 202362, e202303435.
    DOI: 10.1002/anie.202303435
  • A Theory-driven Synthesis of Symmetric and Unsymmetric 1,2-Bis(diphenylphosphino)ethane Analogues via Radical Difunctionalization of Ethylene
    H. Takano, H. Katsuyama, H. Hayashi, W. Kanna, Y. Harabuchi, S. Maeda, T. Mita, Nat. Commun. 2022, 13, 7034.
    DOI: 10.1038/s41467-022-34546-5
  • Prediction of High-Yielding Single-Step or Cascade Pericyclic Reactions for the Synthesis of Complex Synthetic Targets
    T. Mita, H. Takano, H. Hayashi, W. Kanna, Y. Harabuchi, K. N. Houk, S. Maeda, J. Am. Chem. Soc. 2022, 144, 22985.
    DOI: 10.1021/jacs.2c09830
  • Radical Difunctionalization of Gaseous Ethylene Guided by Quantum Chemical Calculations: Selective Incorporation of Two Molecules of Ethylene
    H. Takano, Y. You, H. Hayashi, Y. Harabuchi, S. Maeda, T. Mita, ACS Omega, 2021, 6, 33846-33854.
    DOI: 10.1021/acsomega.1c05102
  • Catalytic Enantioselective Synthesis of Axially Chiral Polycyclic Aromatic Hydrocarbons (PAHs) via Regioselective C-C Bond Activation of Biphenylenes
    H. Takano, N. Shiozawa, Y. Imai, K. S. Kanyiva and T. Shibata, J. Am. Chem. Soc., 2020, 142, 4714-4722.
    DOI: 10.1021/jacs.9b12205
  • Recent Advances of Biphenylene: Synthesis, Reactions and Uses
    H. Takano, T. Ito, K. S. Kanyiva, T. Shibata, Eur. J. Org. Chem., 2019, 2019, 2871–2883.
    DOI: 10.1002/ejoc.201900111
  • Regioselective Activation of a Sterically More Hindered C-C Bond of Biphenylenes Using an Alkene as Both a Directing Group and a Reaction Moiety
    H. Takano, T. Ito, K. S. Kanyiva, T. Shibata, Chem. Eur. J., 2018, 24, 15173–15177.
    DOI: 10.1002/chem.201804044
  • DFT Studies on the Mechanism of the Iridium-Catalyzed Formal [4 + 1] Cycloaddition of Biphenylene with Alkenes
    H. Takano, N. Sugimura, K. S. Kanyiva, T. Shibata, ACS Omega, 2017, 2, 5228–5234.
    DOI: 10.1021/acsomega.7b00403
  • Iridium-Catalyzed Formal [4+1] Cycloaddition of Biphenylenes with Alkenes Initiated by C-C Bond Cleavage for the Synthesis of 9,9-Disubstituted Fluorenes
    H. Takano, K. S. Kanyiva, T. Shibata, Org.Lett., 2016, 18, 1860-1863.
    DOI: 10.1021/acs.orglett.6b00619

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