About the Research
Research Theme
Physical and strucrtural organic chemistry of conjugated polyimines
Keyword
Imine, π-conjugation, aromaticity
Representative Research Achievements
- Luminescent Coordination Polymers Constructed from a Flexible, Tetradentate Diisopyrazole Ligand and Copper(I) Halide
T. Yoneda, C. Kasai, Y. Manabe, M. Tsurui, Y. Kitagawa, Y. Hasegawa, P. Sarkar, Y. Inokuma, Chem. Asian. J., 2020, 15, 601-605
DOI: 10.1002/asia.201901682 - meso-Diketopyripentaphyrin and Diketopyrihexaphyrin as Macrocyclic Tripyrrinone Ligands for NiII Ions
D. Mori, T. Yoneda,* T. Hoshino, S. Neya, Chem. Asian. J., 2019, 14, 4169-4173
DOI: 10.1002/asia.201901375 - Two-Step Transformation of Aliphatic Polyketones into π-Conjugated Polyimines
Y. Manabe, M. Uesaka, T. Yoneda, Y. Inokuma, J. Org. Chem., 2019, 84, 9957-9964
DOI: 10.1021/acs.joc.9b01119 - [24]Pentaphyrin(2.1.1.1.1): a Strongly Antiaromatic Pentaphyrin
T. Yoneda,* T. Hoshino, S. Neya, J. Org. Chem., 2017, 82, 10737-10741
DOI: 10.1021/acs.joc.7b01998 - PdII Complexes of [44]‐ and [46]Decaphyrins: The Largest Hückel Aromatic and Antiaromatic, and Möbius Aromatic Macrocycles
T. Yoneda, Y. M. Sung, J. M. Lim, D.Kim, A. Osuka, Angew. Chem. Int. Ed., 2014, 53, 13619-13713
DOI: 10.1002/anie.201408506
Related Research
- Windmill-shaped, calix[12]pyrrole analogue discovered via ring expansion from chiral calix[3]pyrrole analogue
- Determining Critical Chain Length for Macromolecular Crystallization of Polyketones
- Cyclic polyketones shown to act as ‘traps’ for alkali metal ions and catalyze halogen exchange reactions
- Unlocking the Mysteries Behind the Synthesis of the “Pigments of Life”
- A fluorescent metal-ion detector generated from a ‘masked’ tetraketone
- Molecular ropes to allow more intuitive material design
Publications
2023
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Chain-Length-Dependent Hydrogen-Bonded Self-Assembly of Terminally Functionalized Discrete Polyketones
, Yumehiro Manabe, Tomoki Yoneda, Yuki Ide, Yasuhide Inokuma, Precis. Chem., 2023, 1, 34–39
DOI: 10.1021/prechem.3c00025
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Toward Calix[2]-Type Macrocycles: Synthesis and Structural Analysis of Cyclic Tetraketone and Highly Strained Furanophane
, Y. H. Sun, T. Mukai, Y. Inaba, T. Yoneda, Y. Ide, J. Pirillo, Y. Hijikata, Y. Inokuma, Journal of Porphyrins and Phthalocyanines, 2023, ,
DOI: 10.1142/s1088424623500189
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Chiral Calix[3]pyrrole Derivatives: Synthesis, Racemization Kinetics, and Ring Expansion to Calix[9] - and Calix[12]pyrrole Analogues
, J. Yang, Y. Kakibayashi, T. Yoneda, Y. Ide, Y. Hijikata, J. Pirillo, R. Saha, J. L. Sessler, Y. Inokuma, Angew. Chem., Int. Ed., 2023, 62, e202301460 (page 6)
DOI: 10.1002/anie.202301460
2022
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Absorption Spectra of Calix[3]pyrrole Analogs as Probes for Contracted Macrocycles
, R. Saha, Y. Inaba, Y. Manabe, T. Yoneda, Y. Ide, Y. Hijikata, Y. Inokuma, Journal of Porphyrins and Phthalocyanines, 2022, ,
DOI: 10.1142/s1088424622500754
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Determination of the Critical Chain Length for Macromolecular Crystallization Using Structurally Flexible Polyketones
, Y. Manabe, Y. Inaba, Y. Kinoshita, J. Pirillo, Y. Hijikata, T. Yoneda, K. I. Shivakumar, S. Tanaka, H. Asakawa, Y. Inokuma, Chem. Sci., 2022, 13, 9848-9854
DOI: 10.1039/d2sc03083g
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Strain-Induced Ring Expansion Reactions of Calix 3 Pyrrole-Related Macrocycles
, Y. Kakibayashi, Y. Ide, J. Pirillo, Y. Hijikata, T. Yoneda, Y. Inokuma, Chem. Eur. J., 2022, 28, e202200056
DOI: 10.1002/chem.202200056
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Alkali Metal Ion Binding Using Cyclic Polyketones
, K. I. Shivakumar, M. Murugavel, Y. Inaba, T. Yoneda, Y. Ide, J. Pirillo, Y. Hijikata, Y. Inokuma, Chem. Commun., 2022, 58, 2971-2974
DOI: 10.1039/d2cc00361a
2021
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Hybrid Eu-III Coordination Luminophore Standing on Two Legs on Silica Nanoparticles for Enhanced Luminescence
, Y. Kitagawa, R. Moriake, P. P. F. da Rosa, M. J. Islam, T. Yoneda, Y. Inokuma, K. Fushimi, Y. Hasegawa, Chem. Eur. J., 2021, 27, 14438-14443
DOI: 10.1002/chem.202102156
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Isopyrazole-Masked Tetraketone: Tautomerism and Functionalization for Fluorescent Metal Ligands
, Y. Manabe, C. Kasai, Y. Inaba, M. Tsurui, Y. Kitagawa, Y. Hasegawa, T. Yoneda, Y. Ide, Y. Inokuma, European Journal of Organic Chemistry, 2021, 2021, 4345-4349
DOI: 10.1002/ejoc.202100784
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Calix 3 Pyrrole: A Missing Link in Porphyrin-Related Chemistry
, Y. Nomata, Y. Ide, J. Pirillo, Y. Hijikata, T. Yoneda, A. Osuka, J. L. Sessler, Y. Inokuma, J. Am. Chem. Soc., 2021, 143, 12355-12360
DOI: 10.1021/jacs.1c06331
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Reversible Redox System of 2-Oxypyritriphyrin(1.2.1) Accompanying Interconversion between 3-Pyridone and 3-Hydroxypyridine Units
, T. Yoneda, Y. Ide, S. Neya, Chem. Asian J., 2021, 16, 1077-1080
DOI: 10.1002/asia.202100200
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Insoluble Pi-Conjugated Polyimine as an Organic Adsorbent for Group 10 Metal Ions
, Y. Hijikata, J. Pirillo, T. Yoneda, Y. Manabe, M. Murugavel, Y. Ide, Y. Inokuma, European Journal of Inorganic Chemistry, 2021, , 1705-1708
DOI: 10.1002/ejic.202100172
2020
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Splitting and Reorientation of Pi-Conjugation by an Unprecedented Photo-Rearrangement Reaction
, Yoneda, T, Kitagawa, Y, Miyata, K, Hasegawa, Y, Inokuma, Y, Chem. Commun., 2020, 56, 348-351
DOI: 10.1039/c9cc09062b
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Aliphatic Polyketones as Classic yet New Molecular Ropes for Structural Diversity in Organic Synthesis
, T. Yoneda, Y. Ide, S. Yoshioka, Chem. Commun., 2020, 56, 9079-9093
DOI: 10.1039/d0cc02977g
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Modular Synthesis of Oligoacetylacetones via Site-Selective Silylation of Acetylacetone Derivatives
, Y. Inaba, H. Shirakura, T. Yoneda, Y. Inokuma, Org. Biomol. Chem., 2020, 18, 3297-3302
DOI: 10.1039/d0ob00501k
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Supramolecular Conformational Control of Aliphatic Oligoketones by Rotaxane Formation
, K. Wada, Y. Baba, T. Yoneda, T. Ogoshi, Y. Inokuma, Org. Lett., 2020, 22, 3224-3228
DOI: 10.1021/acs.orglett.0c01010
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Luminescent Coordination Polymers Constructed from a Flexible, Tetradentate Diisopyrazole Ligand and Copper(I) Halides
, C. Kasai, Y. Manabe, M. Tsurui, Y. Kitagawa, Y. Hasegawa, P. Sarkar, Y. Inokuma, Chem. Asian J., 2020, 15, 601-605
DOI: 10.1002/asia.201901682
2019
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Control over Coordination Self-Assembly of Flexible, Multidentate Ligands by Stepwise Metal Coordination of Isopyrazole Subunits
, Y. Manabe, S. Yoshioka, T. Yoneda, Y. Inokuma, Dalton Trans., 2019, 48, 818-822
DOI: 10.1039/c8dt04935a
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Two-Step Transformation of Aliphatic Polyketones into π-Conjugated Polyimines
, M. Uesaka, T. Yoneda, Y. Inokuma, J. Org. Chem., 2019, 84, 9957-9964
DOI: 10.1021/acs.joc.9b01119